Investigation of the characteristics of a stacked direct borohydride fuel cell for portable applications

被引:24
作者
Kim, Cheolhwan [2 ]
Kim, Kyu-Jung [2 ]
Ha, Man Yeong [1 ]
机构
[1] Pusan Natl Univ, Sch Mech Engn, Pusan 609735, South Korea
[2] LG Elect, Digital Appliance Co Lab, Chang Won 641711, Gyeongnam, South Korea
关键词
direct borohydride fuel cell; hydrogen generation; carbon graphite; maldistribution; stacked cell; two-phase flow;
D O I
10.1016/j.jpowsour.2008.01.082
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
To investigate the possibility of the portable application of a direct borohydride fuel cell (DBFC), weight reduction of the stack and high stacking of the cells are investigated for practical running conditions. For weight reduction, carbon graphite is adopted as the bipolar plate material even though it has disadvantages in tight stacking, which results in stacking loss from insufficient material strength. For high stacking, it is essential to have a uniform fuel distribution among cells and channels to maintain equal electric load on each cell. In particular, the design of the anode channel is important because active hydrogen generation causes non-uniformity in the fuel flow-field of the cells and channels. To reduce the disadvantages of stacking force margin and fuel maldistribution, an O-ring type-sealing system with an internal manifold and a parallel anode channel design is adopted, and the characteristics of a single and a five-cell fuel cell stack are analyzed. By adopting carbon graphite, the stack weight can be reduced by 4.2 times with 12% of performance degradation from the insufficient stacking force. When cells are stacked, the performance exceeds the single-cell performance because of the stack temperature increase from the reduction of the radiation area from the narrow stacking of cells. (C) 2008 Elsevier B.V. All rights reserved.
引用
收藏
页码:114 / 121
页数:8
相关论文
共 22 条
[1]  
Amendola S.C., 1998, US Patent, Patent No. [5, 804, 329, 5804329]
[2]   A novel high power density borohydride-air cell [J].
Amendola, SC ;
Onnerud, P ;
Kelly, MT ;
Petillo, PJ ;
Sharp-Goldman, SL ;
Binder, M .
JOURNAL OF POWER SOURCES, 1999, 84 (01) :130-133
[3]   A safe, portable, hydrogen gas generator using aqueous borohydride solution and Ru catalyst [J].
Amendola, SC ;
Sharp-Goldman, SL ;
Janjua, MS ;
Spencer, NC ;
Kelly, MT ;
Petillo, PJ ;
Binder, M .
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2000, 25 (10) :969-975
[4]   Colloidal Au and Au-alloy catalysts for direct borohydride fuel cells: Electrocatalysis and fuel cell performance [J].
Atwan, Mohammed H. ;
Macdonald, Charles L. B. ;
Northwood, Derek O. ;
Gyenge, Elod L. .
JOURNAL OF POWER SOURCES, 2006, 158 (01) :36-44
[5]   Kinetics of sodium borohydride direct oxidation and oxygen reduction in sodium hydroxide electrolyte -: Part II.: O2 reduction [J].
Chatenet, Marian ;
Micoud, Fabrice ;
Roche, Ivan ;
Chainet, Eric ;
Vondrak, Jiri .
ELECTROCHIMICA ACTA, 2006, 51 (25) :5452-5458
[6]   Influence of operation conditions on direct borohydride fuel cell performance [J].
Cheng, H. ;
Scott, K. .
JOURNAL OF POWER SOURCES, 2006, 160 (01) :407-412
[7]   Direct borohydride fuel cells [J].
de Leon, CP ;
Walsh, FC ;
Pletcher, D ;
Browning, DJ ;
Lakeman, JB .
JOURNAL OF POWER SOURCES, 2006, 155 (02) :172-181
[8]   Two-phase flow analysis in multi-channel [J].
Ha, Man Yeong ;
Kim, Cheol Hwan ;
Jung, Yong Won ;
Heo, Seong Geun .
JOURNAL OF MECHANICAL SCIENCE AND TECHNOLOGY, 2006, 20 (06) :840-848
[9]  
KIM CH, 2007, THESIS NATL U, P117
[10]   Effects of MWNT and GNF on the performance of Sulfur electrode for Li/S battery [J].
Kim, JH ;
Choi, YJ ;
Jeong, SS ;
Cho, KK ;
Kim, KW .
ECO-MATERIALS PROCESSING & DESIGN VI, 2005, 486-487 :598-601