η2(3e)-vinyl complexes and one-electron-transfer reactions:: tris(pentafluorophenyl)borane as a one-electron oxidant

被引：30

作者：

Beddows, CJ

Burrows, AD

Connelly, NG

Green, M ^{[1
]}

Lynam, JM

Paget, TJ

机构：

[1] Univ Bath, Dept Chem, Bath BA2 7AY, Avon, England

[2] Univ Bristol, Sch Chem, Bristol BS8 1TS, Avon, England

来源：

ORGANOMETALLICS | 2001年 / 20卷 / 02期

关键词：

D O I：

10.1021/om0007668

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The eta (2)(3e)-vinyl complex [Mo{=C(Ph)CHPh}{P(OMe)(3)}(2)Cp] is oxidized by [FeCp2](+), [CPh3](+), or B(C6F5)(3) to form the 17-electron. cation [Mo{=C(Ph)CHPh}{P(OMe)(3))(2)Cp](+) which on warming loses H to form the cationic eta (2)(4e)-alkyne complex [Mo(eta (2)-PhC CPh){P(OMe)(3))(2)Cp](+). In the case of the borane there is evidence for a competing reaction between the eta (2)-vinyl complex and the acid (H2O)B(C6F5)(3), a resulting in the formation of a labile trans-stilbene complex.

引用

收藏

页码：231 / 233

页数：3

相关论文

共 37 条

[1] SYNTHESES AND REACTIONS OF ETA-2-VINYL COMPLEXES OF MOLYBDENUM AND TUNGSTEN [M(SC6F5)(ETA-2-C(CF3)C(CF3)(PR3))-(CF3C=CCF3)(CP)] AND [MO(ETA-3-C(CF3)C(CF3)(SPRI))-(CF3C=CCF3)(CP)] (CP=ETA-C5H5) [J].

AGHATABAY, NM ;

CANOIRA, LJ ;

CARLTON, L ;

DAVIDSON, JL .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1991, (05) :1175-1182

[2] Reactions of co-ordinated ligands. Part 39. The synthesis of carbyne complexes from alkyne molybdenum and tungsten cations; formation and crystal structures of [Mo( CCH2BUt){P(OMe)3}2(eta-C5H5)] and [Mo{=C(SiMe3)CH2}{P(OMe)3}2(eta 5-C9H7)] [J].

ALLEN, SR ;

BEEVOR, RG ;

GREEN, M ;

ORPEN, AG ;

PADDICK, KE ;

WILLIAMS, ID .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1987, (03) :591-604

[3] REACTIONS OF COORDINATED LIGANDS .33. MONONUCLEAR ETA-2-VINYL COMPLEXES - SYNTHESIS, STRUCTURE, AND REACTIVITY [J].

ALLEN, SR ;

BEEVOR, RG ;

GREEN, M ;

NORMAN, NC ;

ORPEN, AG ;

WILLIAMS, ID .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1985, (03) :435-450

[4] Structure and bonding in redox-active d(4), d(5) and d(6) alkyne complexes: Metal-alkyne moieties as electron sinks [J].

Bartlett, IM ;

Connelly, NG ;

Orpen, AG ;

Quayle, MJ ;

Rankin, JC .

CHEMICAL COMMUNICATIONS, 1996, (22) :2583-2584

[5] Synthesis, structure, spectroscopy, and reactivity of a metallathiabenzene [J].

Bleeke, JR ;

Hinkle, PV ;

Rath, NP .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1999, 121 (03) :595-596

[6] Reactions of new osmium-dihydride complexes with terminal alkynes:: Metallacyclopropene versus metal-carbyne.: Influence of the alkyne substituent [J].

Buil, ML ;

Eisenstein, O ;

Esteruelas, MA ;

García-Yebra, C ;

Gutiérrez-Puebla, E ;

Oliván, M ;

Oñate, E ;

Ruiz, N ;

Tajada, MA .

ORGANOMETALLICS, 1999, 18 (24) :4949-4959

[7]

Burrows AD, 1999, ANGEW CHEM INT EDIT, V38, P3043, DOI 10.1002/(SICI)1521-3773(19991018)38:20<3043::AID-ANIE3043>3.0.CO

[8]

2-2

[9] Reaction of [W(eta(2)-PhC(2)Ph)(3)(NCMe)] with o-diphenylphosphino-styrene and -allylbenzene; Evidence for novel carbon-carbon double and triple bond cleavage and alkyne insertion reactions [J].

Cairns, GA ;

Carr, N ;

Green, M ;

Mahon, MF .

CHEMICAL COMMUNICATIONS, 1996, (21) :2431-2432

[10] Reactions of co-ordinated ligands .60. Synthesis and reactivity of eta(2)(4e)-alkyne and eta(2)(3e)-vinyl complexes of rhenium [J].

Carfagna, C ;

Carr, N ;

Deeth, RJ ;

Dossett, SJ ;

Green, M ;

Mahon, MF ;

Vaughan, C .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1996, (04) :415-430

← 1 2 3 4 →