A high yielding one-pot, novel synthesis of carbamate esters from alcohols using Mitsunobu's reagent

被引：57

作者：

Chaturvedi, D ^{[1
]}

Kumar, A ^{[1
]}

Ray, S ^{[1
]}

机构：

[1] Cent Drug Res Inst, Div Med Chem, Lucknow 226001, Uttar Pradesh, India

来源：

TETRAHEDRON LETTERS | 2003年 / 44卷 / 41期

关键词：

diethyl azodicarboxylate (DEAD); triphenylphosphine; Mitsunobu's reagent; carbon dioxide; N-alkylcarbamates;

D O I：

10.1016/j.tetlet.2003.08.018

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A novel process for the one-step conversion of primary alcohols into carbamates as protected amines has been developed using Mitsunobu's reagent in the presence of gaseous carbon dioxide. Thus, carbamate esters of the different amines were prepared in very good to excellent yields. (C) 2003 Elsevier Ltd. All rights reserved.

引用

页码：7637 / 7639

页数：3

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