Kinetics of α-pinene isomerization

被引：50

作者：

Allahverdiev, AI

Gunduz, G

Murzin, DY

机构：

[1] LY Karpov Phys Chem Res Inst, Dept Catalysis, Moscow 103064, Russia

[2] Ege Univ, Fac Engn, Dept Chem Engn, TR-35100 Izmir, Turkey

来源：

INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH | 1998年 / 37卷 / 06期

关键词：

D O I：

10.1021/ie970573t

中图分类号：

TQ [化学工业];

学科分类号：

0817 ;

摘要：

The kinetics of pinene isomerization over clinoptilolite with formation of several products has been investigated in a batch reactor at atmospheric pressure. Initially mainly camphene and limonene were produced, and only at relatively high conversions were other secondary products formed. Selectivity values at particular conversions were seen to be independent of catalyst pretreatment, although activity was different. The observed kinetic regularities were modeled on the basis of an elementary step mechanism.

引用

页码：2373 / 2377

页数：5