Graphene-based composite materials with high dielectric permittivity via an in situ reduction method

被引:58
作者
Cui, Lili [1 ]
Lu, Xiaofeng [1 ]
Chao, Danming [1 ]
Liu, Hongtao [1 ]
Li, Yongxin [1 ]
Wang, Ce [1 ]
机构
[1] Jilin Univ, Alan G MacDiarmid Inst, Changchun 130012, Peoples R China
来源
PHYSICA STATUS SOLIDI A-APPLICATIONS AND MATERIALS SCIENCE | 2011年 / 208卷 / 02期
关键词
composites; dielectric permittivity; graphene; HIGH-ENERGY DENSITY; POLYMER; ELECTROSTRICTION; PERCOLATION;
D O I
10.1002/pssa.201026273
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Novel nanocomposites with graphene as conductive filler have been prepared through simple ultrasonic exfoliation of graphite oxide (GO) and subsequent in situ reduction approach. The graphene oxide and graphene nanosheets were characterized by transmission electron microscopy (TEM) and X-ray diffraction (XRD) patterns. The composite materials with graphene as conductive filler exhibited a low value of the percolation threshold (4.08 vol.%). It has been observed that the maximum dielectric permittivity of the composite film with 12.5 vol.% of graphene fillers achieved 2080 at 1000 Hz. (C) 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim
引用
收藏
页码:459 / 461
页数:3
相关论文
共 21 条
[1]   Ceramic-polymer composites with high dielectric constant [J].
Arbatti, Milind ;
Shan, Xiaobing ;
Cheng, Zhongyang .
ADVANCED MATERIALS, 2007, 19 (10) :1369-+
[2]   High-dielectric-constant ceramic-powder polymer composites [J].
Bai, Y ;
Cheng, ZY ;
Bharti, V ;
Xu, HS ;
Zhang, QM .
APPLIED PHYSICS LETTERS, 2000, 76 (25) :3804-3806
[3]   A dielectric polymer with high electric energy density and fast discharge speed [J].
Chu, Baojin ;
Zhou, Xin ;
Ren, Kailiang ;
Neese, Bret ;
Lin, Minren ;
Wang, Qing ;
Bauer, F. ;
Zhang, Q. M. .
SCIENCE, 2006, 313 (5785) :334-336
[4]   Langmuir-Blodgett Assembly of Graphite Oxide Single Layers [J].
Cote, Laura J. ;
Kim, Franklin ;
Huang, Jiaxing .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2009, 131 (03) :1043-1049
[5]   Giant dielectric permittivities in functionalized carbon-nanotube/electroactive-polymer nanocomposites [J].
Dang, Zhi-Min ;
Wang, Lan ;
Yin, Yi ;
Zhang, Qing ;
Lei, Qing-Qua .
ADVANCED MATERIALS, 2007, 19 (06) :852-+
[6]   Advanced Calcium Copper Titanate/Polyimide Functional Hybrid Films with High Dielectric Permittivity [J].
Dang, Zhi-Min ;
Zhou, Tao ;
Yao, Sheng-Hong ;
Yuan, Jin-Kai ;
Zha, Jun-Wei ;
Song, Hong-Tao ;
Li, Jian-Ying ;
Chen, Qiang ;
Yang, Wan-Tai ;
Bai, Jinbo .
ADVANCED MATERIALS, 2009, 21 (20) :2077-2082
[7]   Direct synthesis of poly(arylenedisulfide)/carbon nanosheet composites via the oxidation with graphite oxide [J].
Du, XS ;
Xiao, M ;
Meng, YZ ;
Hay, AS .
CARBON, 2005, 43 (01) :195-197
[8]   High Dielectric Permittivity and Low Percolation Threshold in Nanocomposites Based on Poly(vinylidene fluoride) and Exfoliated Graphite Nanoplates [J].
He, Fuan ;
Lau, Sienting ;
Chan, Helen Laiwa ;
Fan, Jintu .
ADVANCED MATERIALS, 2009, 21 (06) :710-+
[9]   PREPARATION OF GRAPHITIC OXIDE [J].
HUMMERS, WS ;
OFFEMAN, RE .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1958, 80 (06) :1339-1339
[10]   Barium Titanate Nanoparticles with Diblock Copolymer Shielding Layers for High-Energy Density Nanocomposites [J].
Jung, Hyun Min ;
Kang, Ji-Hye ;
Yang, Sung Yun ;
Won, Jong Chan ;
Kim, Yong Seok .
CHEMISTRY OF MATERIALS, 2010, 22 (02) :450-456