A simple method for the conversion of primary alcohols into terminal olefins

被引：21

作者：

Matsushita, M ^{[1
]}

Nagaoka, Y ^{[1
]}

Hioki, H ^{[1
]}

Fukuyama, Y ^{[1
]}

Kodama, M ^{[1
]}

机构：

[1] TOKUSHIMA BUNRI UNIV, FAC PHARMACEUT SCI, YAMASHIRO, TOKUSHIMA 770, JAPAN

来源：

CHEMISTRY LETTERS | 1996年 / 12期

关键词：

D O I：

10.1246/cl.1996.1039

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Treatment of benzyl ethers of primary alcohols with n-butyllithium (n-BuLi) afforded terminal olefins in good yield.

引用

页码：1039 / 1040

页数：2

共 10 条

[1] SYNTHESIS OF (-)-ALPHA-MULTISTRIATIN [J].

CERNIGLIARO, GJ ;

KOCIENSKI, PJ .

JOURNAL OF ORGANIC CHEMISTRY, 1977, 42 (22) :3622-3624

[2] ORGANOSELENIUM CHEMISTRY - FACILE ONE-STEP SYNTHESIS OF ALKYL ARYL SELENIDES FROM ALCOHOLS [J].

GRIECO, PA ;

GILMAN, S ;

NISHIZAWA, M .

JOURNAL OF ORGANIC CHEMISTRY, 1976, 41 (08) :1485-1486

[3] REARRANGEMENT OF BENZYL ETHERS TO CARBINOLS BY POTASSIUM AMIDE - MECHANISM OF ISOMERIZATION OF CARBANIONS INVOLVING 1,2-SHIFTS [J].

HAUSER, CR ;

KANTOR, SW .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1951, 73 (04) :1437-1441

[4] COPPER(II) TRIFLATE, A NEW REAGENT FOR MILD DEHYDRATION OF ALCOHOLS - SYNTHETIC USEFULNESS AND MECHANISTIC INSIGHT [J].

LAALI, K ;

GERZINA, RJ ;

FLAJNIK, CM ;

GERIC, CM ;

DOMBROSKI, AM .

HELVETICA CHIMICA ACTA, 1987, 70 (03) :607-611

[5] ETHER CLEAVAGE WITH ORGANO-ALKALI-METAL COMPOUNDS AND ALKALI-METALS [J].

MAERCKER, A .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1987, 26 (10) :972-989

[6]

Marshall J. A., 1991, COMPREHENSIVE ORGANI, V3, P975

[7] [2,3]-WITTIG SIGMATROPIC REARRANGEMENTS IN ORGANIC-SYNTHESIS [J].

NAKAI, T ;

MIKAMI, K .

CHEMICAL REVIEWS, 1986, 86 (05) :885-902

[8] RECENT RESULTS IN CARBANION CHEMISTRY [J].

SCHOLLKOPF, U .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 1970, 9 (10) :763-+

[9]

Schollkopf U., 1970, ANGEW CHEM, V82, P795

[10] OLEFIN SYNTHESIS - RATE ENHANCEMENT OF ELIMINATION OF ALKYL ARYL SELENOXIDES BY ELECTRON-WITHDRAWING SUBSTITUENTS [J].

SHARPLESS, KB ;

YOUNG, MW .

JOURNAL OF ORGANIC CHEMISTRY, 1975, 40 (07) :947-949

← 1 →