Factors influencing solvent adduct formation by calixarenes in the solid state

被引:41
作者
Asfari, Z
Bilyk, A
Bond, C
Harrowfield, JM
Koutsantonis, GA
Lengkeek, N
Mocerino, M
Skelton, BW
Sobolev, AN
Strano, S
Vicens, J
White, AH
机构
[1] Univ Strasbourg, ECPM, F-67087 Strasbourg 2, France
[2] Univ Western Australia, Sch Biomed & Chem Sci, Crystallog Ctr & Chem, Crawley, WA 6009, Australia
[3] Curtin Univ Technol, Sch Appl Chem, Perth, WA 6000, Australia
关键词
D O I
10.1039/b308214h
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Structural studies of seven very differently functionalised derivatives of calix[4]arene have been used to provide an analysis of the numerous factors which may influence solvent adduct formation by calixarenes. Evidence is presented that even where a solvent guest is included within the calixarene cavity, interactions solely within the cavity cannot be seen as the sole influences upon the guest position and orientation.
引用
收藏
页码:387 / 396
页数:10
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