Silver-catalyzed rearrangement of propargylic sulfinates to allenic sulfones

被引：26

作者：

Harmata, Michael ^{[1
]}

Huang, Chaofeng ^{[1
]}

机构：

[1] Univ Missouri, Dept Chem, Columbia, MO 65211 USA

来源：

ADVANCED SYNTHESIS & CATALYSIS | 2008年 / 350卷 / 7-8期

关键词：

allenes; sigmatropic rearrangements; silver; sulfones;

D O I：

10.1002/adsc.200700447

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

Treatment of propargylic sulfinate esters with 2 mol % of silver hexafluoroantimonate results in the rapid formation of allenic sulfones in essentially quantitative yield.

引用

页码：972 / 974

页数：3

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