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The enhanced performance of ceria with surface sulfation for selective catalytic reduction of NO by NH3

被引：534
作者：
Gu, Tingting
Liu, Yue
Weng, Xiaole [1 ]
Wang, Haiqiang
Wu, Zhongbiao
机构：
[1] Zhejiang Univ, Dept Environm Engn, Hangzhou 310027, Zhejiang, Peoples R China
来源：
CATALYSIS COMMUNICATIONS | 2010年 / 12卷 / 04期
基金：
中国国家自然科学基金;
关键词：
SCR; Surface sulfation; CeO2; NO; NH3; RAY PHOTOELECTRON-SPECTROSCOPY; MANGANESE OXIDE CATALYSTS; NITRIC-OXIDE; MIXED OXIDES; LOW-TEMPERATURES; AMMONIA; SO2; SCR; ADSORPTION; OXIDATION;
D O I：
10.1016/j.catcom.2010.10.003
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070305 [高分子化学与物理];
摘要：
The selective catalytic reduction (SCR) of NO with NH3 over fresh and sulfated CeO2 catalysts had been investigated in this study Experimental results showed that the sulfated CeO2 sample had significantly higher NO conversion than the fresh one and revealed an excellent selectivity to N-2 within the temperature range of 200-570 C By characterizations via BET XRD XPS EDS and TPD it was concluded that the improvement in SCR activity by sulfation might be originated from the Increase of active oxygen species and the enhancement of NH3 chemisorption after surface sulfation both of which were conducive to NH3 activation (C) 2010 Elsevier BV All rights reserved
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收藏
页码：310 / 313
页数：4
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