Synthesis of a carbon monolith with trimodal pores

被引:42
作者
Shi, ZG [1 ]
Feng, YQ [1 ]
Xu, L [1 ]
Da, SL [1 ]
Zhang, M [1 ]
机构
[1] Wuhan Univ, Dept Chem, Wuhan 430072, Peoples R China
关键词
carbon composites; carbonization; scanning electron microscopy; microstructure;
D O I
10.1016/S0008-6223(03)00358-0
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The synthesis of a carbon monolith with a co-continuous structure and trimodal pores by a templating method using a silica monolith was reported. The resultant carbon monolith was characterized by high surface area, micropores, uniform mesopores and macroporosity. The mean pore size and the pore volume of the carbon monolith were found to be less than that of the silica monolith, which was a reflection of the mesopore wall size on the skeleton surface of the silica monolith.
引用
收藏
页码:2677 / 2679
页数:3
相关论文
共 19 条
[1]   Simple silica-particle template synthesis of mesoporous carbons [J].
Han, SJ ;
Hyeon, T .
CHEMICAL COMMUNICATIONS, 1999, (19) :1955-1956
[2]   Novel silica-sol mediated synthesis of high surface area porous carbons [J].
Han, SJ ;
Hyeon, T .
CARBON, 1999, 37 (10) :1645-1647
[3]   Ordered nanoporous arrays of carbon supporting high dispersions of platinum nanoparticles [J].
Joo, SH ;
Choi, SJ ;
Oh, I ;
Kwak, J ;
Liu, Z ;
Terasaki, O ;
Ryoo, R .
NATURE, 2001, 412 (6843) :169-172
[4]   Synthesis of new, nanoporous carbon with hexagonally ordered mesostructure [J].
Jun, S ;
Joo, SH ;
Ryoo, R ;
Kruk, M ;
Jaroniec, M ;
Liu, Z ;
Ohsuna, T ;
Terasaki, O .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2000, 122 (43) :10712-10713
[5]   A low cost route to hexagonal mesostructured carbon molecular sieves [J].
Kim, SS ;
Pinnavaia, TJ .
CHEMICAL COMMUNICATIONS, 2001, (23) :2418-2419
[6]   Fabrication of novel mesocellular carbon foams with uniform ultralarge mesopores [J].
Lee, J ;
Sohn, K ;
Hyeon, T .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2001, 123 (21) :5146-5147
[7]   A facile synthesis of bimodal mesoporous silica and its replication for bimodal mesoporous carbon [J].
Lee, J ;
Kim, J ;
Hyeon, T .
CHEMICAL COMMUNICATIONS, 2003, (10) :1138-1139
[8]   Low-cost and facile synthesis of mesocellular carbon foams [J].
Lee, J ;
Sohn, K ;
Hyeon, T .
CHEMICAL COMMUNICATIONS, 2002, (22) :2674-2675
[9]   Synthesis and adsorption properties of colloid-imprinted carbons with surface and volume mesoporosity [J].
Li, ZJ ;
Jaroniec, M .
CHEMISTRY OF MATERIALS, 2003, 15 (06) :1327-1333
[10]   Synthesis of mesoporous carbon foams templated by organic colloids [J].
Lukens, WW ;
Stucky, GD .
CHEMISTRY OF MATERIALS, 2002, 14 (04) :1665-1670