Indacenodithiophene Semiconducting Polymers for High-Performance, Air-Stable Transistors

被引：531

作者：

Zhang, Weimin ^{[1
,2
]}

Smith, Jeremy ^{[1
]}

Watkins, Scott E.

Gysel, Roman ^{[3
]}

McGehee, Michael ^{[3
]}

Salleo, Alberto ^{[3
]}

Kirkpatrick, James ^{[1
]}

Ashraf, Shahid ^{[1
]}

Anthopoulos, Thomas ^{[1
]}

Heeney, Martin ^{[1
]}

McCulloch, Iain ^{[1
]}

机构：

[1] Univ London Imperial Coll Sci Technol & Med, London SW7 2AZ, England

[2] Guangxi Univ Nationalities, Nanning 530006, Peoples R China

[3] Stanford Univ, Stanford, CA 94305 USA

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2010年 / 132卷 / 33期

关键词：

CHARGE-CARRIER MOBILITY; COPOLYMERS;

D O I：

10.1021/ja1049324

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

High-performance, solution-processed transistors fabricated from semiconducting polymers containing indacenodithiohene repeat units are described. The bridging functions on the backbone contribute to suppressing large-scale crystallization in thin films. However, charge carrier mobilities of up to 1 cm(2)/(V s) for a benzothiadiazole copolymer were reported and, coupled with both ambient stability and long-wavelength absorption, make this family of polymers particularly attractive for application in next-generation organic optoelectronics.

引用

页码：11437 / 11439

页数：3

共 8 条

[1] Synthesis, characterization, and photovoltaic properties of novel semiconducting polymers with thiophene-phenylene-thiophene (TPT) as coplanar units [J].

Chan, Shu-Hua ;

Chen, Chih-Ping ;

Chao, Teng-Chih ;

Ting, Ching ;

Lin, Chin-Sheng ;

Ko, Bao-Tsan .

MACROMOLECULES, 2008, 41 (15) :5519-5526

[2] Tetrathienoacene copolymers as high mobility, soluble organic semiconductors [J].

Fong, Hon Hang ;

Pozdin, Vladimir A. ;

Amassian, Aram ;

Malliaras, George G. ;

Smilgies, Detlef-M. ;

He, Mingqian ;

Gasper, Susan ;

Zhang, Feixia ;

Sorensen, Michael .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2008, 130 (40) :13202-13203

[3] High-Performance Polymer-Small Molecule Blend Organic Transistors [J].

Hamilton, Richard ;

Smith, Jeremy ;

Ogier, Simon ;

Heeney, Martin ;

Anthony, John E. ;

McCulloch, Iain ;

Veres, Janos ;

Bradley, Donal D. C. ;

Anthopoulos, Thomas D. .

ADVANCED MATERIALS, 2009, 21 (10-11) :1166-1171

[4] Liquid-crystalline semiconducting polymers with high charge-carrier mobility [J].

Mcculloch, I ;

Heeney, M ;

Bailey, C ;

Genevicius, K ;

Macdonald, I ;

Shkunov, M ;

Sparrowe, D ;

Tierney, S ;

Wagner, R ;

Zhang, WM ;

Chabinyc, ML ;

Kline, RJ ;

Mcgehee, MD ;

Toney, MF .

NATURE MATERIALS, 2006, 5 (04) :328-333

[5] Microwave-assisted synthesis of polythiophenes via the Stille coupling [J].

Tierney, S ;

Heeney, M ;

McCulloch, I .

SYNTHETIC METALS, 2005, 148 (02) :195-198

[6] The Influence of Morphology on High-Performance Polymer Field-Effect Transistors [J].

Tsao, Hoi Nok ;

Cho, Don ;

Andreasen, Jens Wenzel ;

Rouhanipour, Ali ;

Breiby, Dag W. ;

Pisula, Wojciech ;

Muellen, Klaus .

ADVANCED MATERIALS, 2009, 21 (02) :209-+

[7] A high-mobility electron-transporting polymer for printed transistors [J].

Yan, He ;

Chen, Zhihua ;

Zheng, Yan ;

Newman, Christopher ;

Quinn, Jordan R. ;

Dotz, Florian ;

Kastler, Marcel ;

Facchetti, Antonio .

NATURE, 2009, 457 (7230) :679-U1

[8] Systematic Improvement in Charge Carrier Mobility of Air Stable Triarylamine Copolymers [J].

Zhang, Weimin ;

Smith, Jeremy ;

Hamilton, Rick ;

Heeney, Martin ;

Kirkpatrick, James ;

Song, Kigook ;

Watkins, Scott E. ;

Anthopoulos, Thomas ;

McCulloch, Iain .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2009, 131 (31) :10814-+

← 1 →