Electroactive Organic Molecules Immobilized onto Solid Nanoparticles as a Cathode Material for Lithium-Ion Batteries

被引：173

作者：

Genorio, Bostjan ^{[2
]}

Pirnat, Klemen ^{[1
]}

Cerc-Korosec, Romana ^{[2
]}

Dominko, Robert ^{[1
]}

Gaberscek, Miran ^{[1
,2
]}

机构：

[1] Natl Inst Chem, Lab Mat Electrochem, Ljubljana, Slovenia

[2] Univ Ljubljana, Fac Chem & Chem Technol, Ljubljana, Slovenia

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2010年 / 49卷 / 40期

关键词：

calixarenes; electrochemistry; immobilization; lithium; quinones; SELF-ASSEMBLED MONOLAYER; REDOX; ELECTRODE; POLYMER;

D O I：

10.1002/anie.201001539

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Active monomers : Crafting soluble organic molecules onto insoluble, high-surface-area substrates, e.g. calixqui-nones on nanoparticles (see pciture), allows the production of a wide range of very stable materials for lithium-ion battery applications. Immobilization of the organic molecules avoids the problem of dissolution, which has previously led to performance degradation. © 2010 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：7222 / 7224

页数：3

共 15 条

[1] Building better batteries [J].

Armand, M. ;

Tarascon, J. -M. .

NATURE, 2008, 451 (7179) :652-657

[2]

Armand M, 2009, NAT MATER, V8, P120, DOI [10.1038/nmat2372, 10.1038/NMAT2372]

[3] Electrochemical functionalization of a gold electrode with redox-active self-assembled monolayer for electroanalytical application [J].

Behera, Susmita ;

Sampath, S. ;

Raj, C. Retna .

JOURNAL OF PHYSICAL CHEMISTRY C, 2008, 112 (10) :3734-3740

[4]

CASNATI A, 1993, RECL TRAV CHIM PAY B, V112, P384

[5] From biomass to a renewable LixC6O6 organic electrode for sustainable Li-ion batteries [J].

Chen, Haiyan ;

Armand, Michel ;

Demailly, Gilles ;

Dolhem, Franck ;

Poizot, Philippe ;

Tarascon, Jean-Marie .

CHEMSUSCHEM, 2008, 1 (04) :348-355

[6] Lithium Salt of Tetrahydroxybenzoquinone: Toward the Development of a Sustainable Li-Ion Battery [J].

Chen, Haiyan ;

Armand, Michel ;

Courty, Matthieu ;

Jiang, Meng ;

Grey, Clare P. ;

Dolhem, Franck ;

Tarascon, Jean-Marie ;

Poizot, Philippe .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2009, 131 (25) :8984-8988

[7] Chemical overcharge and overdischarge protection for lithium-ion batteries [J].

Chen, J ;

Buhrmester, C ;

Dahn, JR .

ELECTROCHEMICAL AND SOLID STATE LETTERS, 2005, 8 (01) :A59-A62

[8] Self-assembled monolayer of a redox-active calix[4]arene:: Voltammetric recognition of the Ba2+ ion in aqueous media [J].

Chung, TD ;

Park, J ;

Kim, J ;

Lim, H ;

Choi, MJ ;

Kim, JR ;

Chang, SK ;

Kim, H .

ANALYTICAL CHEMISTRY, 2001, 73 (16) :3975-3980

[9]

Gutsche C.D., 1989, Calixarenes

[10]

Lee SW, 2010, NAT NANOTECHNOL, V5, P531, DOI [10.1038/NNANO.2010.116, 10.1038/nnano.2010.116]

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