Chiral amplification in the transcription of supramolecular helicity into a polymer backbone

被引：122

作者：

Wilson, AJ ^{[1
]}

Masuda, M ^{[1
]}

Sijbesma, RP ^{[1
]}

Meijer, EW ^{[1
]}

机构：

[1] Eindhoven Univ Technol, Lab Macromol & Organ Chem, NL-5600 MB Eindhoven, Netherlands

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2005年 / 44卷 / 15期

关键词：

helical structures; polymerization; polymers; self-assembly; supramolecular chemistry;

D O I：

10.1002/anie.200462347

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Figure Presented) A chiral supramolecular sergeant" as the structure-directing agent affects the backbone stereochemistry during polymerization of the achiral "soldier" monomers. The polymer obtained shows preferred helical folding despite its mixed microstructure. © 2005 Wiley-VCH Verlag GmbH & Co. KGaA."

引用

页码：2275 / 2279

页数：5

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