Yb3O(OH)6Cl•2H2O: An Anion-Exchangeable Hydroxide with a Cationic Inorganic Framework Structure

被引：66

作者：

Goulding, Helen V. ^{[1
]}

Hulse, Sarah E. ^{[1
]}

Clegg, William ^{[2
]}

Harrington, Ross W. ^{[2
]}

Playford, Helen Y. ^{[3
]}

Walton, Richard I. ^{[3
]}

Fogg, Andrew M. ^{[1
]}

机构：

[1] Univ Liverpool, Dept Chem, Liverpool L69 7ZD, Merseyside, England

[2] Newcastle Univ, Sch Chem, Newcastle Upon Tyne NE1 7RU, Tyne & Wear, England

[3] Univ Warwick, Dept Chem, Coventry CV4 7AL, W Midlands, England

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2010年 / 132卷 / 39期

基金：

英国工程与自然科学研究理事会;

关键词：

LAYERED DOUBLE HYDROXIDES; CRYSTAL-STRUCTURES; LN; FAMILY; ER; ALUMINOPHOSPHATES; EU; BR; GD; CL;

D O I：

10.1021/ja104636x

中图分类号：

O6 [化学];

学科分类号：

070301 [无机化学];

摘要：

The first anion-exchangeable framework hydroxide, Yb3O(OH)(6)Cl center dot 2H(2)O, has been synthesized hydrothermally. This material has a three-dimensional cationic ytterbium oxyhydroxide framework with one-dimensional channels running through the structure in which the chloride anions and water molecules are located. The framework is thermally stable below 200 degrees C and can be reversibly dehydrated and rehydrated with no loss of crystallinity. Additionally, it is able to undergo anion-exchange reactions with small ions such as carbonate, oxalate, and succinate with retention of the framework structure.

引用

页码：13618 / 13620

页数：3

共 22 条

[1]

Baerlocher Ch., 2007, ATLAS ZEOLITE STRUCT, V6th

[2]

Dyer A., 1988, INTRO ZEOLITE MOL SI

[3]

A SYNTHETIC GALLOPHOSPHATE MOLECULAR-SIEVE WITH A 20-TETRAHEDRAL-ATOM PORE OPENING [J].

ESTERMANN, M ;

MCCUSKER, LB ;

BAERLOCHER, C ;

MERROUCHE, A ;

KESSLER, H .

NATURE, 1991, 352 (6333) :320-323

[4]

Structural aspects of layered double hydroxides [J].

Evans, DG ;

Slade, RCT .

LAYERED DOUBLE HYDROXIDES, 2006, 119 :1-87

[5]

Applications of layered double hydroxides [J].

Feng, L ;

Duan, X .

LAYERED DOUBLE HYDROXIDES, 2006, 119 :193-223

[6]

New Layered Rare-Earth Hydroxides with Anion-Exchange Properties [J].

Geng, Fengxia ;

Xin, Hao ;

Matsushita, Yoshitaka ;

Ma, Renzhi ;

Tanaka, Masahiko ;

Izumi, Fujio ;

Iyi, Nobuo ;

Sasaki, Takayoshi .

CHEMISTRY-A EUROPEAN JOURNAL, 2008, 14 (30) :9255-9260

[7]

General Synthesis and Structural Evolution of a Layered Family of Ln8(OH)20Cl4•nH2O (Ln = Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, and Y) [J].

Geng, Fengxia ;

Matsushita, Yoshitaka ;

Mat, Renzhi ;

Xin, Hao ;

Tanaka, Masahiko ;

Izumi, Fujio ;

Iyi, Nobuo ;

Sasaki, Takayoshi .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2008, 130 (48) :16344-16350

[8]

Precipitation synthesis of lanthanide hydroxynitrate anion exchange materials, Ln2(OH)5NO3 • H2O (Ln = Y, Eu-Er) [J].

Hindocha, Sheena A. ;

McIntyre, Laura J. ;

Fogg, Andrew M. .

JOURNAL OF SOLID STATE CHEMISTRY, 2009, 182 (05) :1070-1074

[9]

Extended Members of the Layered Rare-Earth Hydroxide Family, RE2(OH)5NO3•nH2O (RE = Sm, Eu, and Gd): Synthesis and Anion-Exchange Behavior [J].

Lee, Kyung-Hee ;

Byeon, Song-Ho .

EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2009, (07) :929-936

[10]

The pervasive chemistry of metal-organic frameworks [J].

Long, Jeffrey R. ;

Yaghi, Omar M. .

CHEMICAL SOCIETY REVIEWS, 2009, 38 (05) :1213-1214

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