Li6PS5X:: A class of crystalline Li-rich solids with an unusually high Li+ mobility

被引：889

作者：

Deiseroth, Hans-Joerg ^{[1
]}

Kong, Shiao-Tong ^{[1
]}

Eckert, Hellmut ^{[2
]}

Vannahme, Julia ^{[2
]}

Reiner, Christof ^{[1
]}

Zaiss, Torsten ^{[1
]}

Schlosser, Marc ^{[1
]}

机构：

[1] Univ Siegen, D-57068 Siegen, Germany

[2] Univ Munster, Inst Phys Chem, D-48149 Munster, Germany

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2008年 / 47卷 / 04期

关键词：

argyrodites; conducting materials; halides; lithium; NMR spectroscopy;

D O I：

10.1002/anie.200703900

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Figure Presented) Mobile metal ions: Halide-substituted lithium argyrodites form a new class of Li-rich solids with an unusually high Li mobility. Single-crystal X-ray studies (see picture; Li black, S yellow, I red) at room temperature and MAS-NMR measurements in a wide temperature range provide insights into the Li+ ion dynamics. © 2008 Wiley-VCH Verlag GmbH & Co. KGaA.

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页码：755 / 758

页数：4

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