A new reverse PET chemosensor and its chelatoselective aromatic cadmiation

被引:122
作者
Choi, M
Kim, M
Lee, KD
Han, KN
Yoon, IA
Chung, HJ
Yoon, J [1 ]
机构
[1] Silla Univ, Dept New Mat Chem, Pusan 617736, South Korea
[2] Silla Univ, Nanophoton Res Ctr, Pusan 617736, South Korea
[3] Silla Univ, Dept Food & Nutr, Pusan 617736, South Korea
[4] Donguk Univ, Dept Chem, Kyungju, Kyungbuk, South Korea
关键词
D O I
10.1021/ol016400o
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
[GRAPHICS] A new fluorescent chemosensor, anthryl tetra acid, was synthesized and showed large fluorescence quenching effects in 100% aqueous solution with metal ions via photoinduced electron transfer (PET). Chelatoselective fluorescence perturbation was observed with Cd(II) and resulted from electrophilic aromatic cadmiation.
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页码:3455 / 3457
页数:3
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