Trivalent aluminum ionic conduction in the aluminum tungstate scandium tungstate lutetium tungstate solid solution system

被引：41

作者：

Tamura, S ^{[1
]}

Egawa, T ^{[1
]}

Okazaki, Y ^{[1
]}

Kobayashi, Y ^{[1
]}

Imanaka, N ^{[1
]}

Adachi, G ^{[1
]}

机构：

[1] Osaka Univ, Fac Engn, Dept Appl Chem, Osaka 5650871, Japan

来源：

CHEMISTRY OF MATERIALS | 1998年 / 10卷 / 07期

关键词：

D O I：

10.1021/cm980115q

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The solid solutions of the Al-2(WO4)(3)-SC2(WO4)(3)-Lu-2(WO4)(3) Series which hold the SC2(WO4)(3)-type structure were prepared and their ionic conducting characteristics were investigated. The maximum electrical conductivity was obtained for the solid solution of (Al-2(WO4)(3))(0.1)((Sc0.5Lu0.5)(2)(WO4)(3))(0.9) BY the measurements of the electrical conductivity dependencies on oxygen pressure and the polarization analyses, the mobile species in the solid solution was found to be only ionic and also oxide anion was eliminated from the candidates of the conducting ion species. Among the cation species in the solid solution, the mobile ion was demonstrated to be only Al3+ ion and the rest of the cations such as SC3+, Lu3+, and W6+ functioned as lattice-forming ions with oxide anion from the electrolysis experiments. Here, the highest Al3+ ion conduction was obtained in the Sc-2(WO4)(3)-type structure and the optimal lattice size for the Al3+ ion migration in the Sc-2(WO4)(3)-type structure was identified.

引用

页码：1958 / 1962

页数：5

共 19 条

[1] CRYSTAL STRUCTURE OF TRANSITION-METAL MOLYBDATES AND TUNGSTATES .2. DIAMAGNETIC SC2(WO4)3 [J].