Trifluoropropynylxenon(II) tetrafluoroborate [CF3CCXe] [BF4] -: isolation of an alkynylxenon(II) compound for the first time

被引：19

作者：

Frohn, HJ

Bardin, VV

机构：

[1] Univ Duisburg Essen, Inst Chem, D-47048 Duisburg, Germany

[2] SB RAS, NN Vorozhtsov Novosibirsk Inst Organ Chem, Novosibirsk 630090, Russia

来源：

CHEMICAL COMMUNICATIONS | 2003年 / 18期

关键词：

D O I：

10.1039/b307583d

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The salt [CF(3)Cequivalent toCXe] [BF4] was prepared as neat compound by the reaction of the hitherto unknown alkynyldifluoroborane CF(3)Cequivalent toCBF(2) with XeF2 in 1,1,1,3,3-pentafluoropropane (PFP) at -45 degreesC in 59% yield. [CF(3)Cequivalent toCXe] [BF4] was unambiguously characterised by multinuclear NMR spectroscopy in anhydrous HF (aHF) solution.

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页码：2352 / 2353

页数：2

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