A new form of manganese carbonate for the negative electrode of lithium-ion batteries

被引：91

作者：

Jose Aragon, Maria ^{[1
]}

Leon, Bernardo ^{[1
]}

Perez Vicente, Carlos ^{[1
]}

Tirado, Jose L. ^{[1
]}

机构：

[1] Univ Cordoba, Lab Quim Inorgan, E-14071 Cordoba, Spain

来源：

JOURNAL OF POWER SOURCES | 2011年 / 196卷 / 05期

关键词：

Manganese carbonate; Lithium batteries; Conversion reactions; NANOCOMPOSITES; SPINEL; OXIDE;

D O I：

10.1016/j.jpowsour.2010.11.032

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A reverse micelles method is used in the synthesis of manganese carbonate. The use of cetyltrimethylammonium bromide surfactant and hexanol cosurfactant allows the preparation of a new monodispersed form of MnCO3. Particles with a regular shape and ca. 200 nm edges are observed by electron microscopy. The electrochemical reaction with lithium of the manganese carbonate leads to the formation of the manganese metal and lithium carbonate as the main side product, which yields higher capacity than graphite and good capacity retention. Submicron MnCO3 could replace other more toxic and expensive anodes used in recent commercial Li-ion products. (C) 2010 Elsevier B.V. All rights reserved.

引用

页码：2863 / 2866

页数：4

共 13 条

[1] NiCo2O4 spinel:: First report on a transition metal oxide for the negative electrode of sodium-ion batteries [J].

Alcántara, R ;

Jaraba, M ;

Lavela, P ;

Tirado, JL .

CHEMISTRY OF MATERIALS, 2002, 14 (07) :2847-+

[2] Submicronic particles of manganese carbonate prepared in reverse micelles:: A new electrode material for lithium-ion batteries [J].

Aragon, M. J. ;

Perez-Vicente, C. ;

Tirado, J. L. .

ELECTROCHEMISTRY COMMUNICATIONS, 2007, 9 (07) :1744-1748

[3] THE SURFACE-CHEMISTRY OF LITHIUM ELECTRODES IN ALKYL CARBONATE SOLUTIONS [J].

AURBACH, D ;

EINELY, Y ;

ZABAN, A .

JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1994, 141 (01) :L1-L3

[4] Structure and electrochemistry of copper fluoride nanocomposites utilizing mixed conducting matrices [J].

Badway, F. ;

Mansour, A. N. ;

Pereira, N. ;

Al-Sharab, J. F. ;

Cosandey, F. ;

Plitz, I. ;

Amatucci, G. G. .

CHEMISTRY OF MATERIALS, 2007, 19 (17) :4129-4141

[5]

BECK WA, 1946, BUR MINES REP INVEST, V3858, P5

[6] Templated Nanocrystal-Based Porous TiO2 Films for Next-Generation Electrochemical Capacitors [J].

Brezesinski, Torsten ;

Wang, John ;

Polleux, Julien ;

Dunn, Bruce ;

Tolbert, Sarah H. .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2009, 131 (05) :1802-1809

[7] X-ray absorption spectroscopic study of LiCoO2 as the negative electrode of lithium-ion batteries [J].

Chadwick, Alan V. ;

Savin, Shelley L. P. ;

Alcantara, Ricardo ;

Lisbona, Diego Fernandez ;

Lavela, Pedro ;

Ortiz, Gregorio F. ;

Tirado, Jose L. .

CHEMPHYSCHEM, 2006, 7 (05) :1086-1091

[8] Electrospun manganese oxide nanofibers as anodes for lithium-ion batteries [J].

Fan, Quan ;

Whittingham, M. Stanley .

ELECTROCHEMICAL AND SOLID STATE LETTERS, 2007, 10 (03) :A48-A51

[9]

IRANI KS, 1958, J SCI INDIAN RES B, V17, P52

[10] Cobalt Oxalate Nanoribbons as Negative-Electrode Material for Lithium-Ion Batteries [J].

Jose Aragon, Maria ;

Leon, Bernardo ;

Perez Vicente, Carlos ;

Tirado, Jose L. ;

Chadwick, Alan V. ;

Berko, Aaron ;

Beh, See-Yuen .

CHEMISTRY OF MATERIALS, 2009, 21 (09) :1834-1840

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