Optical resolution of racemic alcohols by diastereoisomeric complex formation with O,O'-dibenzoyl-(2R,3R)-tartaric acid; The crystal structure of the (-)-(1R,2S,5R)-menthol center dot O,O'-dibenzoyl-(2R,3R)-tartaric acid complex

被引：18

作者：

Kozma, D ^{[1
]}

Bocskei, Z ^{[1
]}

Kassai, C ^{[1
]}

Simon, K ^{[1
]}

Fogassy, E ^{[1
]}

机构：

[1] CHINOIN CHEM & PHARMACEUT WORKS LTD, H-1325 BUDAPEST, HUNGARY

来源：

CHEMICAL COMMUNICATIONS | 1996年 / 06期

关键词：

D O I：

10.1039/cc9960000753

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

O,O'-dibenzoyl-(2R,3R)-tartaric acid resolves racemic alcohols by complex formation; the X-ray crystal structure of the (-)-(1R,2S,5R)-menthol . O,O'-dibenzoyl-(2R,3R)-tartaric acid complex is reported which was obtained by reacting O,O'-dibenzoyl-(2R,3R)-tartaric acid monohydrate and racemic menthol.

引用

页码：753 / 754

页数：2

共 10 条

[1] ENCODING AND DECODING HYDROGEN-BOND PATTERNS OF ORGANIC-COMPOUNDS [J].

ETTER, MC .

ACCOUNTS OF CHEMICAL RESEARCH, 1990, 23 (04) :120-126

[2]

Jacques J., 1981, Enantiomers, Racemates and Resolutions

[3] Study of the diastereoisomers formed between (N-alkyl)-pipecolic acid-anilides and 2R,3R-tartaric acid or O,O'-dibenzoyl-2R,3R-tartaric acid. Do the tartaric acids form molecular-complexes, instead of salts during optical resolutions? [J].

Nemak, K ;

Acs, M ;

Jaszay, ZM ;

Kozma, D ;

Fogassy, E .

TETRAHEDRON, 1996, 52 (05) :1637-1642

[4] CHIRAL ALKOXYTITANIUM(IV) COMPLEXES FOR ENANTIOSELECTIVE NUCLEOPHILIC ADDITIONS TO ALDEHYDES AND AS LEWIS-ACIDS IN DIELS-ALDER REACTIONS [J].

SEEBACH, D ;

BECK, AK ;

IMWINKELRIED, R ;

ROGGO, S ;

WONNACOTT, A .

HELVETICA CHIMICA ACTA, 1987, 70 (04) :954-974

[5]

Sheldon R.A., 1993, CHIROTECHNOLOGY

[6] STRUCTURE AND INCLUSION CHARACTERISTICS OF (R,R)-(-)-2,3-DIMETHOXY-1,1,4,4-TETRAPHENYLBUTANE-1,4-DIOL [J].

TODA, F ;

TANAKA, K ;

STEIN, Z ;

GOLDBERG, I .

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2, 1993, (12) :2359-2361

[7] NOVEL OPTICAL RESOLUTION METHODS BY INCLUSION CRYSTALLIZATION IN SUSPENSION MEDIA AND BY FRACTIONAL DISTILLATION [J].

TODA, F ;

TOHI, Y .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1993, (15) :1238-1240

[8] ROLE OF METHANOL IN CHIRAL COMBINATIONS OF HOST-GUEST MOLECULES IN THE INCLUSION CRYSTAL - STRUCTURE DETERMINATION BY X-RAY CRYSTALLOGRAPHY [J].

TODA, F ;

TANAKA, K ;

MIYAHARA, I ;

AKUTSU, S ;

HIROTSU, K .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1994, (15) :1795-1796

[9]

TODA F, 1987, TOP CURR CHEM, V140, P44

[10] NEW CHIRAL SELECTORS DERIVED FROM LACTIC-ACID - COCRYSTALLINE AND SORPTIVE OPTICAL RESOLUTIONS, AND THE CRYSTAL-STRUCTURE OF AN INCLUSION COMPLEX WITH 3-METHYLCYCLOHEXANONE [J].

WEBER, E ;

WIMMER, C ;

LLAMASSAIZ, AL ;

FOCESFOCES, C .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1992, (10) :733-735

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