Demonstration of the parity-violating energy difference between enantiomers

被引:82
作者
Szabó-Nagy, A [1 ]
Keszthelyi, L [1 ]
机构
[1] Hungarian Acad Sci, Biol Res Ctr, Inst Biophys, H-6701 Szeged, Hungary
关键词
D O I
10.1073/pnas.96.8.4252
中图分类号
O [数理科学和化学]; P [天文学、地球科学]; Q [生物科学]; N [自然科学总论];
学科分类号
07 ; 0710 ; 09 ;
摘要
Racemic mixtures of (+) and (-) sodium potassium tartrate, tris (1,2-ethanediamine)cobalt(III), and tris (1,2-ethanediamine) iridium(III) molecules were crystallized, and the optical activities of the resulting crystalline materials, dissolved in water, were carefully measured to study the influence of the parity-violating energy difference in the crystallization process, Although no effect was found in the case of tartrate, enantiomeric excess appeared in the crystallization of the cobalt and iridium complexes. These investigations, performed in our laboratory, demonstrated the contribution of the parity-violating neutral weak current to the forces acting in molecules.
引用
收藏
页码:4252 / 4255
页数:4
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