Ethylenebis(phosphonic acid)

被引：12

作者：

Bruckmann, J ^{[1
]}

Krüger, C ^{[1
]}

Lehmann, CW ^{[1
]}

Leitner, W ^{[1
]}

Rust, J ^{[1
]}

Six, C ^{[1
]}

机构：

[1] Max Planck Inst Kohlenforsch, D-45470 Mulheim, Germany

来源：

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 1999年 / 55卷

关键词：

D O I：

10.1107/S0108270198016448

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The as yet structurally uncharacterized title compound, C2H8O4P2, was isolated as a by-product of the synthesis of 1,2-bis(dimethylphosphino)ethane (dmpe) from 1,2-bis (dichlorophosphino) ethane. In the crystal structure, which is characterized by strong intermolecular O-H ... Osp(2) hydrogen bonds, only the R*,S* diastereomer is found. The molecule is located on a center of inversion intersecting the central C-C bond, thereby preserving the molecular C-i symmetry.

引用

页码：695 / 696

页数：2

共 9 条

[1]

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[2] CONVENIENT SYNTHESIS OF 1,2-BIS(DICHLOROPHOSPHINO)ETHANE, 1,2-BIS(DIMETHYLPHOSPHINO)ETHANE AND 1,2-BIS(DIETHYLPHOSPHINO)ETHANE [J].

BURT, RJ ;

CHATT, J ;

HUSSAIN, W ;

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[3]

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[4]

*ENR, 1995, CAD 4 EXPRESS VERS 5

[5]

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[6]

KING C, 1996, INORG CHEM, V25, P1290

[7]

Saenger W., 1991, HYDROGEN BONDING BIO

[8]

Sheldrick G.M., 1997, SHELXTL-97

[9] PHASE ANNEALING IN SHELX-90 - DIRECT METHODS FOR LARGER STRUCTURES [J].

SHELDRICK, GM .

ACTA CRYSTALLOGRAPHICA SECTION A, 1990, 46 :467-473

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