Two-dimensional network constructed from hexamolybdate, octamolybdate and [Cu3(4,7-phen)3]3+ clusters:: [{Cu3(4,7-phen)3}2{Mo14O45}]

被引：193

作者：

Hagrman, D ^{[1
]}

Zapf, PJ ^{[1
]}

Zubieta, J ^{[1
]}

机构：

[1] Syracuse Univ, Dept Chem, Syracuse, NY 13244 USA

来源：

CHEMICAL COMMUNICATIONS | 1998年 / 12期

关键词：

D O I：

10.1039/a801742e

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The hydrothermal reaction of Cu(SO4). H2O, MoO3, 4,7-phenanthroline and water yields [(Cu-3(4,7-phen)(3))(2)(Mo14O45)], a material exhibiting a two-dimensional network constructed from (Mo6O19)(2-) and (Mo8O26)(4-) clusters linked through planar cyclic [Cu-3(4,7-phen)(3)(3))(+) clusters.

引用

收藏

页码：1283 / 1284

页数：2

相关论文

共 20 条

[1] New solids from old clusters: Syntheses and structure of [Cu(en)(2)](2)[Mo8O26], [Cu(enMe)(2)](3)[V15O36Cl].2.5H(2)O and Cs-0.5[Ni(en)(2)](3)[V18O42Cl].2en.6H(2)O [J].

DeBord, JRD ;

Haushalter, RC ;

Meyer, LM ;

Rose, DJ ;

Zapf, PJ ;

Zubieta, J .

INORGANICA CHIMICA ACTA, 1997, 256 (02) :165-168

[2] A NOVEL CHAIN-LIKE HETEROPOLYANION FORMED BY KEGGIN UNITS - SYNTHESIS AND STRUCTURE OF (ET)(8N)[PMNW11O39](N)CENTER-DOT-2NH(2)O [J].

GALANMASCAROS, JR ;

GIMENEZSAIZ, C ;

TRIKI, S ;

GOMEZGARCIA, CJ ;

CORONADO, E ;

OUAHAB, L .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1995, 34 (13-14) :1460-1462

[3] CHIMIE DOUCE APPROACHES TO THE SYNTHESIS OF METASTABLE OXIDE MATERIALS [J].

GOPALAKRISHNAN, J .

CHEMISTRY OF MATERIALS, 1995, 7 (07) :1265-1275

[4]

Greenwood N.N., 1984, CHEM ELEMENTS

[5] Composite solids constructed from one-dimensional coordination polymer matrices and molybdenum oxide subunits: Polyoxomolybdate clusters within [{Cu(4,4'-bpy)}(4)Mo8O26] and [{Ni(H2O)(2)(4,4'-bpy)(2)}(2)Mo8O26] and one-dimensional oxide chains in [{Cu(4,4'-bpy)}(4)Mo15O47]center dot 8H(2)O [J].

Hagrman, D ;

Zubieta, C ;

Rose, DJ ;

Zubieta, J ;

Haushalter, RC .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1997, 36 (08) :873-876

[6] REDUCED MOLYBDENUM PHOSPHATES - OCTAHEDRAL TETRAHEDRAL FRAMEWORK SOLIDS WITH TUNNELS, CAGES, AND MICROPORES [J].

HAUSHALTER, RC ;

MUNDI, LA .

CHEMISTRY OF MATERIALS, 1992, 4 (01) :31-48

[7]

HENCH LL, 1995, ACS SERIES, P523

[8] Giant voids in the hydrothermally synthesized microporous square pyramidal tetrahedral framework vanadium phosphates [HN(CH2CH2)(3)NH]K-1.35[V5O9(PO4)(2)]center dot xH(2)O and Cs-3[V5O9(PO4)(2)]center dot xH(2)O [J].

Khan, MI ;

Meyer, LM ;

Haushalter, RC ;

Schweitzer, AL ;

Zubieta, J ;

Dye, JL .

CHEMISTRY OF MATERIALS, 1996, 8 (01) :43-53

[9] ORDERED MESOPOROUS MOLECULAR-SIEVES SYNTHESIZED BY A LIQUID-CRYSTAL TEMPLATE MECHANISM [J].

KRESGE, CT ;

LEONOWICZ, ME ;

ROTH, WJ ;

VARTULI, JC ;

BECK, JS .

NATURE, 1992, 359 (6397) :710-712

[10] Synthesis, structure of polymeric cobalt-containing heteropolytungstates and their applications in oxidation catalysis [J].

Loose, I ;

Bosing, M ;

Klein, R ;

Krebs, B ;

Schulz, RP ;

Scharbert, B .

INORGANICA CHIMICA ACTA, 1997, 263 (1-2) :99-108