Temperature-composition phase diagram of the organic alloys, λ-BETS2(FeXGa1-X)Cl4, with mixed magnetic and non-magnetic anions

被引:55
作者
Sato, A
Ojima, E
Akutsu, H
Kobayashi, H [1 ]
Kobayashi, A
Cassoux, P
机构
[1] Grad Univ Adv Studies, Okazaki, Aichi 444, Japan
[2] Inst Mol Sci, Okazaki, Aichi 444, Japan
[3] Univ Tokyo, Sch Sci, Dept Chem, Tokyo 113, Japan
[4] CNRS, LCC, Equipe Precurseurs Mol & Mat, F-31077 Toulouse, France
关键词
D O I
10.1246/cl.1998.673
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The electrical properties of a series of lambda-type BETS conductors, lambda-BETS2(FexGa1-x)Cl-4 can be controlled continuously by varying the x-value. The system shows a metal-insulator transition for x>x(1) (x(1)approximate to 0.5) and a superconducting transition for x<x(1). The T-x phase diagram indicates that the system shows the superconductor-insulator transition for x(2)<x<x(1) (x(2)approximate to 0.35).
引用
收藏
页码:673 / 674
页数:2
相关论文
共 10 条
[1]   Highly correlated organic conductor with magnetic anions exhibiting a π-d coupled metal-insulator transition, λ-(BETS)2FeBrxCl4-x (BETS = bis(ethylenedithio)tetraselenafulvalene) [J].
Akutsu, H ;
Arai, E ;
Kobayashi, H ;
Tanaka, H ;
Kobayashi, A ;
Cassoux, P .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1997, 119 (51) :12681-12682
[2]  
BRAVOV LI, 1990, IAN SSSR KH, V1, P206
[3]   Interplay between chains of S=5/2 localised spins and two-dimensional sheets of organic donors in the synthetically built magnetic multilayer λ-(BETS)2FeCl4 [J].
Brossard, L ;
Clerac, R ;
Coulon, C ;
Tokumoto, M ;
Ziman, T ;
Petrov, DK ;
Laukhin, VN ;
Naughton, MJ ;
Audouard, A ;
Goze, F ;
Kobayashi, A ;
Kobayashi, H ;
Cassoux, P .
EUROPEAN PHYSICAL JOURNAL B, 1998, 1 (04) :439-452
[4]   STRUCTURE AND PROPERTIES OF TRIS[BIS(ETHYLENEDITHIO)TETRATHIAFULVALENIUM]TETRACHLOROCOPPER(II) HYDRATE, (BEDT-TTF)3CUCL4.H2O - 1ST EVIDENCE FOR COEXISTENCE OF LOCALIZED AND CONDUCTION ELECTRONS IN A METALLIC CHARGE-TRANSFER SALT [J].
DAY, P ;
KURMOO, M ;
MALLAH, T ;
MARSDEN, IR ;
FRIEND, RH ;
PRATT, FL ;
HAYES, W ;
CHASSEAU, D ;
GAULTIER, J ;
BRAVIC, G ;
DUCASSE, L .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1992, 114 (27) :10722-10729
[5]   NEW ORGANIC METALS BASED ON BETS COMPOUNDS WITH MX4- ANIONS (BETS=BIS(ETHYLENEDITHIO)TETRASELENAFULVALENE - M = GA, FE, IN X = CL, BR) [J].
KOBAYASHI, A ;
UDAGAWA, T ;
TOMITA, H ;
NAITO, T ;
KOBAYASHI, H .
CHEMISTRY LETTERS, 1993, (12) :2179-2182
[6]   Superconductor-to-insulator transition in an organic metal incorporating magnetic anions:: λ-(BETS)2(FexGa1-x)Cl4 [BETS = bis(ethylenedithio)tetraselenafulvalene;: x≈0.55 and 0.43] [J].
Kobayashi, H ;
Sato, A ;
Arai, E ;
Akutsu, H ;
Kobayashi, A ;
Cassoux, P .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1997, 119 (50) :12392-12393
[7]   Electric and magnetic properties and phase diagram of a series of organic superconductors lambda-BETS2GaXzY4-z [BETS=bis(ethylenedithiotetraselenafulvalene; X, Y=F, Cl, Br; 0<z<2)] [J].
Kobayashi, H ;
Akutsu, H ;
Arai, E ;
Tanaka, H ;
Kobayashi, A .
PHYSICAL REVIEW B, 1997, 56 (14) :R8526-R8529
[8]   New BETS conductors with magnetic anions (BETS equivalent to bis(ethylenedithio)tetraselenafulvalene) [J].
Kobayashi, H ;
Tomita, H ;
Naito, T ;
Kobayashi, A ;
Sakai, F ;
Watanabe, T ;
Cassoux, P .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1996, 118 (02) :368-377
[9]   SUPERCONDUCTING AND SEMICONDUCTING MAGNETIC CHARGE-TRANSFER SALTS - (BEDT-TTF)(4)AFE(C(2)O4)(3)CENTER-DOT-C6H5CN (A=H2O, K, NH4) [J].
KURMOO, M ;
GRAHAM, AW ;
DAY, P ;
COLES, SJ ;
HURSTHOUSE, MB ;
CAULFIELD, JL ;
SINGLETON, J ;
PRATT, FL ;
HAYES, W ;
DUCASSE, L ;
GUIONNEAU, P .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1995, 117 (49) :12209-12217
[10]  
TANAKA N, 1996, ADV MATER, V8, P812