Vanadium chloride and chloride oxide complexes in an ambient-temperature ionic liquid. The first use of bis(trichloromethyl) carbonate as a substitute for phosgene in an inorganic system

被引：13

作者：

Dent, AJ

Lees, A

Lewis, RJ

Welton, T

机构：

[1] UNIV LONDON IMPERIAL COLL SCI & TECHNOL,DEPT CHEM,LONDON SW7 2AY,ENGLAND

[2] DARESBURY LAB,CLRC,WARRINGTON WA4 4AD,CHESHIRE,ENGLAND

[3] QUEENS UNIV BELFAST,SCH CHEM,BELFAST BT9 5AG,ANTRIM,NORTH IRELAND

[4] UNIV EXETER,DEPT CHEM,EXETER EX4 4QD,DEVON,ENGLAND

来源：

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 1996年 / 13期

关键词：

D O I：

10.1039/dt9960002787

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The oxo exchange chemistry of vanadium chloride and chloride oxide complexes in solution in a room-temperature ionic liquid has been investigated, using a number of reagents. The structures of the solute species have been elucidated using a combination of electronic absorption spectroscopy and extended X-ray absorption fine structure. The reagent bis(trichloromethyl) carbonate has been used as a substitute for phosgene (COCl2) in an inorganic system for the first time.

引用

页码：2787 / 2792

页数：6

共 30 条

[1] THE REMOVAL OF OXIDE IMPURITIES FROM ROOM-TEMPERATURE HALOGENOALUMINATE IONIC LIQUIDS [J].

ABDULSADA, AK ;

AVENT, AG ;

PARKINGTON, MJ ;

RYAN, TA ;

SEDDON, KR ;

WELTON, T .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1987, (21) :1643-1644

[2] A FAST-ATOM-BOMBARDMENT MASS-SPECTROMETRIC STUDY OF ROOM-TEMPERATURE 1-ETHYL-3-METHYLIMIDAZOLIUM CHLOROALUMINATE(III) IONIC LIQUIDS - EVIDENCE FOR THE EXISTENCE OF THE DECACHLOROTRIALUMINATE(III) ANION [J].

ABDULSADA, AK ;

GREENWAY, AM ;

SEDDON, KR ;

WELTON, T .

ORGANIC MASS SPECTROMETRY, 1993, 28 (07) :759-765

[3]

ABDULSADA AK, 1994, J CHEM SOC DA, P3283

[4] DIOXODIFLUORO-VANADATE(V) AND DIOXODICHLORO-VANADATE(V) IONS [J].

AHLBORN, E ;

DIEMANN, E ;

MULLER, A .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1972, (07) :378-&

[5]

CAREY JV, 1989, THESIS U SUSSEX

[6] COMPLEXES OF TITANIUM TRICHLORIDE [J].

CLARK, RJH ;

MACHIN, DJ ;

LEWIS, J ;

NYHOLM, RS .

JOURNAL OF THE CHEMICAL SOCIETY, 1963, (JAN) :379-&

[7]

DARRAN JC, 1975, ACTA CRYSTALLOGR B, V31, P1833

[8] PREPARATION AND ELECTRONIC SPECTRA OF SOME OXIDE CHLORIDE COMPLEXES OF VANADIUM-(IV) AND -(V) WITH A MOLECULAR ORBITAL TREATMENT OF VOCI42-ION [J].

DRAKE, JE ;

VEKRIS, JE ;

WOOD, JS .

JOURNAL OF THE CHEMICAL SOCIETY A -INORGANIC PHYSICAL THEORETICAL, 1969, (03) :345-&

[9]

du Preez J. G. H., 1967, INORG CHIM ACTA, V1, P202

[10] REACTION OF ALKYL CYANIDES WITH CHLORIDES AND BROMIDES OF TERVALENT TITANIUM AND VANADIUM, AND WITH VANADIUM(IV) CHLORIDE [J].

DUCKWORTH, MW ;

HOODLESS, RA ;

FOWLES, GWA .

JOURNAL OF THE CHEMICAL SOCIETY, 1963, (DEC) :5665-&

← 1 2 3 →