An electrochemical investigation of a Sn-Co-C ternary alloy as a negative electrode in Li-ion batteries

被引:85
作者
Hassoun, J.
Panero, S.
Mulas, G.
Scrosati, B. [1 ]
机构
[1] Univ Roma La Sapienza, Dept Chem, I-00185 Rome, Italy
[2] Univ Sassari, Dept Chem, I-07100 Sassari, Italy
关键词
alloy; ternary; electrode; lithium; battery; LITHIUM BATTERIES;
D O I
10.1016/j.jpowsour.2007.06.067
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
This work reports an electrochemical investigation of a Sn-Co-C ternary electrode which supposedly is similar to that adopted in a new lithium-ion commercial battery. The electrode, obtained by mechanical-milling of Sn, Co and C (graphite), and having the Sn31Co28C41 composition, shows very promising electrochemical characteristics both in terms of specific capacity and rate. The practical relevance of this electrode is demonstrated by using it as anode in a new type of lithium-ion battery which cycles with a good capacity and with a high coulombic efficiency. (C) 2007 Elsevier B.V. All rights reserved.
引用
收藏
页码:928 / 931
页数:4
相关论文
共 16 条
  • [1] The Ni3Sn4 intermetallic as a novel electrode in lithium cells
    Amadei, I
    Panero, S
    Scrosati, B
    Cocco, G
    Schiffini, L
    [J]. JOURNAL OF POWER SOURCES, 2005, 143 (1-2) : 227 - 230
  • [2] Fine-particle lithium iron phosphate LiFePO4 synthesized by a new low-cost aqueous precipitation technique
    Arnold, G
    Garche, J
    Hemmer, R
    Ströbele, S
    Vogler, C
    Wohlfahrt-Mehrens, A
    [J]. JOURNAL OF POWER SOURCES, 2003, 119 : 247 - 251
  • [3] New insights into the interactions between electrode materials and electrolyte solutions for advanced nonaqueous batteries
    Aurbach, D
    Markovsky, B
    Levi, MD
    Levi, E
    Schechter, A
    Moshkovich, M
    Cohen, Y
    [J]. JOURNAL OF POWER SOURCES, 1999, 81 : 95 - 111
  • [4] Anomalous, high-voltage irreversible capacity in tin electrodes for lithium batteries
    Beattie, SD
    Hatchard, T
    Bonakdarpour, A
    Hewitt, KC
    Dahn, JR
    [J]. JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2003, 150 (06) : A701 - A705
  • [5] The electrochemical reaction of lithium with tin studied by in situ AFM
    Beaulieu, LY
    Beattie, SD
    Hatchard, TD
    Dahn, JR
    [J]. JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2003, 150 (04) : A419 - A424
  • [6] FILMING MECHANISM OF LITHIUM-CARBON ANODES IN ORGANIC AND INORGANIC ELECTROLYTES
    BESENHARD, JO
    WINTER, M
    YANG, J
    BIBERACHER, W
    [J]. JOURNAL OF POWER SOURCES, 1995, 54 (02) : 228 - 231
  • [7] Combinatorial study of Sn1-xCox (0 < x < 0.6) and [Sn0.55Co0.45]1-yCy (0 < y < 0.5) alloy negative electrode materials for Li-ion batteries
    Dahn, JR
    Mar, RE
    Abouzeid, A
    [J]. JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2006, 153 (02) : A361 - A365
  • [8] Ternary Sn-Co-CLi-ion battery electrode material prepared by high energy ball milling
    Hassoun, J.
    Mulas, G.
    Panero, S.
    Scrosati, B.
    [J]. ELECTROCHEMISTRY COMMUNICATIONS, 2007, 9 (08) : 2075 - 2081
  • [9] Inoue H., 2006, INT M LITH BATT IMLB
  • [10] Sodium carboxymethyl cellulose - A potential binder for Si negative electrodes for Li-ion batteries
    Li, Jing
    Lewis, R. B.
    Dahn, J. R.
    [J]. ELECTROCHEMICAL AND SOLID STATE LETTERS, 2007, 10 (02) : A17 - A20