Oxidative dehydrogenation of propane by continuous and periodic operating flow reactor with a nickel molybdate catalyst

被引：17

作者：

Del Rosso, R ^{[1
]}

Kaddouri, A ^{[1
]}

Anouchinsky, R ^{[1
]}

Mazzocchia, C ^{[1
]}

Gronchi, P ^{[1
]}

Centola, P ^{[1
]}

机构：

[1] Politecn Milan, Dipartimento Chim Ind & Ingn Chim, I-20133 Milan, Italy

来源：

JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL | 1998年 / 135卷 / 02期

关键词：

oxidative dehydrogenation of propane; periodic operating flow reactor; nickel molybdate;

D O I：

10.1016/S1381-1169(97)00302-6

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Oxidative dehydrogenation of propane with nickel molybdate catalysts (alpha NiMoO4) has been investigated in flow reactors feeding the reactant gases continuously and periodically. The data obtained by the continuous operating system (COS) showed the determining role of lattice oxygen on the selectivity. Moreover, when only the lattice oxygen was consumed, very high propene selectivity was obtained. (C) 1998 Elsevier Science B.V. All rights reserved.

引用

页码：181 / 186

页数：6

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