Reduction of conjugate double bonds with trichlorosilane

被引：7

作者：

Chauhan, M ^{[1
]}

Boudjouk, P ^{[1
]}

机构：

[1] N Dakota State Univ, Dept Chem, Ctr Main Grp Chem, Fargo, ND 58105 USA

来源：

CANADIAN JOURNAL OF CHEMISTRY-REVUE CANADIENNE DE CHIMIE | 2000年 / 78卷 / 11期

关键词：

reduction; carbonyl compounds; trichlorosilane; ketones; chemoselectivity;

D O I：

10.1139/cjc-78-11-1396

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A variety of alpha,beta -unsaturated esters and cyclic ketones underwent smooth reduction of the carbon-carbon double bond with a combination of inexpensive and readily available trichlorosilane and CoCl2. The reactions are performed under very mild conditions and products are obtained in high yields.

引用

页码：1396 / 1398

页数：3

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