Transition-metal complexes featuring z-type ligands:: Agreement or discrepancy between geometry and dn configuration?

被引：198

作者：

Sircoglou, Marie

Bontemps, Sebastien

Mercy, Maxime

Saffon, Nathalie

Takahashi, Masashi

Bouhadir, Ghenwa

Maron, Laurent

Bourissou, Didier

机构：

[1] Univ Toulouse 3, CNRS, UMR 5069, Lab Heterochim Fondamentale & Appl, F-31062 Toulouse 09, France

[2] Univ Toulouse 3, Lab Phys & Chim Nanoobjets, INSA, UMR 5215, F-31077 Toulouse, France

[3] Univ Toulouse 3, Struct Federat Toulousaine Chim Mol, FR 2599, F-31062 Toulouse 09, France

[4] Toho Univ, Fac Sci, Dept Chem, Chiba 2748510, Japan

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2007年 / 46卷 / 45期

关键词：

B; P ligands; donor-acceptor systems; electronic structure; gold; Mossbauer spectroscopy;

D O I：

10.1002/anie.200703518

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Chemical Equation Presented) The value of gold: The coordination of ambiphilic diphosphanylborane ligands to AuCl provides unusual square-planar gold(I) complexes. Insight is gained on the nature of the gold→borane interactions in these complexes through natural bond orbital (NBO) analysis and 197Au Mössbauer spectroscopy. © 2007 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：8583 / 8586

页数：4

共 69 条

[1] Mesitylborane as a bis(σ-B-H) ligand:: An unprecedented bonding mode to a metal center [J].