A powerful new oxidation agent towards metallic gold powder:: N,N′-dimethylperhydrodiazepine-2,3-dithione (D) bis(diiodine).: Synthesis and X-ray structure of [AuDI2]I3

被引：43

作者：

Bigoli, F

Deplano, P

Mercuri, ML

Pellinghelli, MA

Pintus, G

Serpe, A

Trogu, EF

机构：

[1] Univ Cagliari, Dipartimento Chim & Tecnol Inorgan & Met Organ, I-09124 Cagliari, Italy

[2] CSSD CNR, Dipartimento Chim Gen & Inorgan, I-43100 Parma, Italy

来源：

CHEMICAL COMMUNICATIONS | 1998年 / 21期

关键词：

D O I：

10.1039/a806158k

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The oxidation of gold powder by a new safe and powerful oxidising reagent, the bis-diiodine adduct of N,N'-dimethylperhydrodiazepine-2,3-dithione (D), to produce [AuI2D]I-3 under ambient conditions is described.

引用

页码：2351 / 2352

页数：2

共 17 条

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