The role of FeS and (NH4)2CO3 additives on the pressed type Fe electrode

被引：56

作者：

Caldas, CA ^{[1
]}

Lopes, MC ^{[1
]}

Carlos, IA ^{[1
]}

机构：

[1] UFSCar, DQ, Grp Electrochem & Polymers, BR-13565905 Sao Carlos, SP, Brazil

来源：

JOURNAL OF POWER SOURCES | 1998年 / 74卷 / 01期

关键词：

Ni-Fe batteries; porous electrodes; passivation; iron sulfide; ammonium carbonate;

D O I：

10.1016/S0378-7753(98)00039-1

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

In the present work the influence of the FeS and (NH4)(2)CO3 additives on the Ni-Fe battery negative plate was studied through galvanostatic and potentiostatic discharges. Some aspects of the Fe electrode discharge mechanism in the presence of the FeS were elucidated. The presence of (NH4)(2)CO3 as pore forming agent in the Fe electrode was advantageous since it increased the capacity. (C) 1998 Elsevier Science S.A. All rights reserved.

引用

页码：108 / 112

页数：5

共 12 条

[1] COMPARATIVE-STUDY OF POROUS IRON ELECTRODES
CERNY, J
JINDRA, J
MICKA, K
[J]. JOURNAL OF POWER SOURCES, 1993, 45 (03) : 267 - 279
[2] CERNY J, 1976, J ELECTROCHEM SOC, V123, P1691
[3] THE NICKEL IRON BATTERY
CHAKKARAVARTHY, C
PERIASAMY, P
JEGANNATHAN, S
VASU, KI
[J]. JOURNAL OF POWER SOURCES, 1991, 35 (01) : 21 - 35
[4] The kinetic mechanism of the PbO2 discharge of the lead/acid positive plates
DAlkaine, CV
Carubelli, A
Lopes, MC
[J]. JOURNAL OF POWER SOURCES, 1997, 64 (1-2) : 111 - 115
[5] THE ENERGETIC COEFFICIENT IN LEAD-ACID-BATTERY POSITIVE PLATES
DALKAINE, CV
DOSSANTOS, MAS
AVACA, LA
[J]. JOURNAL OF POWER SOURCES, 1990, 30 (1-4) : 153 - 158
[6] DALKAINE CV, 1995, P 11 CIBAE 9 SIBEE A
[7] Falk S.V., 1969, ALKALINE STORAGE BAT, V1
[8] ROLE OF ACTIVATION ON THE PERFORMANCE OF THE IRON NEGATIVE ELECTRODE IN NICKEL IRON CELLS
JAYALAKSHMI, M
BEGUM, BN
CHIDAMBARAM, VR
SABAPATHI, R
MURALIDHARAN, VS
[J]. JOURNAL OF POWER SOURCES, 1992, 39 (01) : 113 - 119
[9] PRIASAMY P, 1996, J POWER SOURCES, V63, P79
[10] SEMYONOV L, 1977, STORAGE BATTERIES MA, P24

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