Simultaneous functional group manipulation in the Meerwein-Ponndorf-Verley reduction process catalyzed by bidentate aluminum reagent

被引:34
作者
Ooi, T [1 ]
Itagaki, Y [1 ]
Miura, T [1 ]
Maruoka, K [1 ]
机构
[1] Hokkaido Univ, Grad Sch Sci, Dept Chem, Sapporo, Hokkaido 0600810, Japan
关键词
D O I
10.1016/S0040-4039(99)00131-8
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Simultaneous reduction/oxidation sequence of hydroxy carbonyl substrates through Meerwein-Ponndorf-Verley reduction can be facilitated in the presence of bidentate aluminum catalyst, (2,7-dimethyl-1,8-biphenylenedioxy)bis(dimethylaluminum This new approach provides the opportunity for efficient hydride transfer between two remotely situated functional groups, (C) 1999 Elsevier Science Ltd. All rights reserved.
引用
收藏
页码:2137 / 2138
页数:2
相关论文
共 4 条
[1]  
Larock R. C., 1989, COMPREHENSIVE ORGANI
[2]  
Ooi T, 1998, ANGEW CHEM INT EDIT, V37, P2347, DOI 10.1002/(SICI)1521-3773(19980918)37:17<2347::AID-ANIE2347>3.0.CO
[3]  
2-U
[4]   (2,7-dimethyl-1,8-biphenylenedioxy)bis(dimethyl-aluminum) as a bidentate Lewis acid: Its reactivity and selectivity in organic synthesis [J].
Ooi, T ;
Takahashi, M ;
Maruoka, K .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1996, 118 (45) :11307-11308