Pentacyanoferrate(III)-μ-cyano-[triaquatetrakis(dimethylformamide)gadolinium(III)] monohydrate

被引：11

作者：

Li, JR

Cai, LZ

Guo, GC ^{[1
]}

Bu, XH

Huang, JS

机构：

[1] Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Peoples R China

[2] Nankai Univ, Dept Chem, Tianjin 300071, Peoples R China

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2004年 / 60卷

关键词：

D O I：

10.1107/S160053680400193X

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

The crystal structure of the title complex, [Gd(C3H 6NO)4(H2O)3(μ-CN){Fe(CN) 5}]·H2O, is built of neutral bimetallic Gd-Fe complexes and solvent water molecules. The GdIII atom, with the coordination of a distorted square antiprism, and the octahedral six-coordinated FeIII atom are bridged by an almost linear cyanide link [Fe-C = 1.934 (2) Å, C-N = 1.149 (2) Å, N-Gd = 2.449 (2) Å, Fe-C-N = 177.2 (2)°, C-N-Gd = 162.6 (1)° and Fe⋯Gd = 5.457 (3) Å]. Intermolecular O-H⋯O and O-H⋯N hydrogen bonds link the molecules into a three-dimensional framework. © 2004 International Union of Crystallography Printed in Great Britain - all rights reserved.

引用

页码：M259 / M261

页数：3

共 13 条

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[2]

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[3]

GIGUEROLA A, 2003, INORG CHEM, V42, P641

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