Visible light C-H amidation of heteroarenes with benzoyl azides

被引：149

作者：

Brachet, E. ^{[1
]}

Ghosh, T. ^{[1
]}

Ghosh, I. ^{[1
]}

Koenig, B. ^{[1
]}

机构：

[1] Univ Regensburg, Fac Chem & Pharm, Inst Organ Chem, D-93053 Regensburg, Germany

来源：

CHEMICAL SCIENCE | 2015年 / 6卷 / 02期

关键词：

ACYL AZIDES; PHOTOREDOX CATALYSIS; AMINATION; PHOTOCHEMISTRY; CYCLOADDITION; CHEMISTRY; ARENES; SULFONYL; ACID;

D O I：

10.1039/c4sc02365j

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Benzoyl azides were used for the direct and atom economic C-H amidation of electron rich heteroarenes in the presence of phosphoric acid, a photocatalyst and visible light. Hetero-aromatic amides are obtained in good yields at very mild reaction conditions with dinitrogen as the only by-product. The reaction allows the use of aryl-, heteroaryl- or alkenyl acyl azides and has a wide scope for heteroarenes, including pyrroles, indole, furan, benzofuran and thiophene giving good regio-selectivities and yields.

引用

页码：987 / 992

页数：6

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