Carbanion-mediated photocages: Rapid and efficient photorelease with aqueous compatibility

被引：59

作者：

Lukeman, M ^{[1
]}

Scaiano, JC ^{[1
]}

机构：

[1] Univ Ottawa, Dept Chem, Ottawa, ON K1N 6N5, Canada

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2005年 / 127卷 / 21期

关键词：

D O I：

10.1021/ja0517062

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A new photocage is proposed, based on ketoprofen-derived compounds and mediated by carbanions. The new photocage has significant advantages over the widely used o-nitrobenzyl derivatives, including aqueous compatibility, faster photorelease, higher quantum yield, and innocuous byproducts. The photorelease of ibuprofen illustrates the properties of the new photocage. Copyright © 2005 American Chemical Society.

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页码：7698 / 7699

页数：2

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