A pincer-type anionic platinum(0) complex

被引：30

作者：

Schwartsburd, Leonid ^{[1
]}

Cohen, Revital ^{[2
]}

Konstantinovski, Leonid ^{[2
]}

Milstein, David ^{[1
]}

机构：

[1] Weizmann Inst Sci, Dept Organ Chem, IL-76100 Rehovot, Israel

[2] Weizmann Inst Sci, Unit Chem Res Support, IL-76100 Rehovot, Israel

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2008年 / 47卷 / 19期

关键词：

C-F activation; electron transfer; P ligands; platinum; reduction;

D O I：

10.1002/anie.200705927

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Chemical Presented) Holding a Pt0 anion in a pincer: Reduction of the pincer-type PtII complex 1 results in the formation of the thermally stable anionic Pt0 complex 2. This complex adopts a T-shaped structure and exhibits diverse reactivity, including efficient electron-transfer processes in which 2 is reoxidized quantitatively to Pt II. Protonation of 2 with water gives a PtII hydride complex, and C-F activation under mild conditions leads to 3 (see scheme). © 2008 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：3603 / 3606

页数：4

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