Recent advances in direct arylation via palladium-catalyzed aromatic C-H activation

被引：656

作者：

Li, Bi-Jie

Yang, Shang-Dong

Shi, Zhang-Jie ^{[1
]}

机构：

[1] Peking Univ, Beijing Natl Lab Mol Sci, Minist Educ, Coll Chem, Beijing 100871, Peoples R China

来源：

SYNLETT | 2008年 / 07期

关键词：

C-H activation; arylation; palladium; catalysis; acetanilide;

D O I：

10.1055/s-2008-1042907

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Highly selective arylation catalyzed by palladium and directed by the acetamino group provides an efficient and practical protocol for constructing unique biaryl scaffolds, which could be further transformed into different structural units found in a range of natural products. 1 Introduction 2 Highly Regioselective Halogenation 3 Highly Regioselective Arylation 3.1 With Arylboronic Acids 3.2 With Trialkoxyarylsilanes 3.3 With Simple Arenes 3.4 Further Transformations 4 Conclusion.

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收藏

页码：949 / 957

页数：9

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