Elastic, dielectric, and piezoelectric anomalies and Raman spectroscopy of 0.5Ba(Ti0.8Zr0.2)O3-0.5(Ba0.7Ca0.3)TiO3

被引:155
作者
Damjanovic, Dragan [1 ]
Biancoli, Alberto [1 ]
Batooli, Leili [1 ]
Vahabzadeh, Amirhossein [1 ]
Trodahl, Joe [2 ]
机构
[1] Swiss Fed Inst Technol Lausanne EPFL, Ceram Lab, CH-1015 Lausanne, Switzerland
[2] Victoria Univ, MacDiarmid Inst Adv Mat & Nanotechnol, Wellington, New Zealand
关键词
BARIUM-TITANATE; SINGLE-CRYSTALS; CERAMICS; MOTION;
D O I
10.1063/1.4714703
中图分类号
O59 [应用物理学];
学科分类号
摘要
The solid solution 0.5Ba(Ti0.8Zr0.2)O-3-0.5(Ba0.7Ca0.3)TiO3 (BCZT) is a promising lead-free piezoelectric material with exceptionally high piezoelectric coefficients. The strong response is related to structural instabilities close to ambient temperature. We report here on temperature-induced anomalies in the dielectric, piezoelectric, and elastic coefficients and Raman spectroscopy of ceramic BCZT. The data indicate ferroelectric-ferroelectric structural phase transitions in this material in addition to those previously reported. An anomaly is also observed above the Curie temperature T-C and is associated with the loss of polar structure that persists thirty degrees above T-C. (C) 2012 American Institute of Physics. [http://dx.doi.org/10.1063/1.4714703]
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页数:4
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