Polyhalogenated heterocyclic compounds. part 50. Macrocycles from perfluoro-4-isopropylpyridine

被引:68
作者
Chambers, RD
Hoskin, PR
Kenwright, AR
Khalil, A
Richmond, P
Sandford, G
Yufit, DS
Howard, JAK
机构
[1] Univ Durham, Dept Chem, Durham DH1 3LE, England
[2] Univ Durham, Chem Crystallog Unit, Durham DH1 3LE, England
关键词
D O I
10.1039/b303443g
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Perfluoro-4-isopropylpyridine was used as a building block for the two-step synthesis of a variety of macrocyclic systems bearing pyridine sub-units which were characterised by X-ray crystallography. Electrospray mass spectrometry revealed that complexation of either cations and, unusually, anions is possible depending on the structure of the macrocycle.
引用
收藏
页码:2137 / 2147
页数:11
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