Controlled self-assembly triggered by olefin metathesis:: Cross-linked graphitic nanotubes from an amphiphilic hexa-peri-hexabenzocoronene

被引：94

作者：

Jin, W

Fukushima, T

Kosaka, A

Niki, M

Ishii, N

Aida, T

机构：

[1] Natl Museum Emerging Sci & Innovat, Japan Sci & Technol Agcy, JST,Aida Nanospace Project, ERATO,Koto Ku, Tokyo 1350064, Japan

[2] Natl Inst Adv Ind Sci & Technol, AIST, Biol Informat Res Ctr, Tsukuba, Ibaraki 3058566, Japan

[3] Univ Tokyo, Sch Engn, Dept Chem & Biotechnol, Bunkyo Ku, Tokyo 1138656, Japan

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2005年 / 127卷 / 23期

关键词：

D O I：

10.1021/ja051859p

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Acyclic diene metathesis (ADMET) in CH2Cl2 of a Gemini-shaped nonionic hexabenzocoronene amphiphile (2), bearing triethylene glycol chains with terminal allylic functionalities, resulted in spontaneous formation of graphitic nanotubes with a cross-linked surface. Without ADMET, 2 did not self-assemble to form a tubular structure due to a high solubility in CH2Cl2. Although 2 formed nanotubes in THF, ADMET on the surface of the preformed nanotubes in THF proceeded only sluggishly and resulted in partial disruption of the tubular structure. The cross-linked nanotubes showed a softening temperature (244 °C) higher than that of the uncross-linked version (195 °C) and preserved their hollow structure much longer upon heating. Copyright © 2005 American Chemical Society.

引用

页码：8284 / 8285

页数：2

共 21 条

[1] Polyphenylene nanostructures [J].

Berresheim, AJ ;

Müller, M ;

Müllen, K .

CHEMICAL REVIEWS, 1999, 99 (07) :1747-1785

[2] Homogeneous metathesis polymerization by well-defined group VI and group VIII transition-metal alkylidenes: Fundamentals and applications in the preparation of advanced materials [J].

Buchmeiser, MR .

CHEMICAL REVIEWS, 2000, 100 (04) :1565-1604

[3]

CLARK CG, 2002, DENDRIMER OTHER DEND, P147

[4]

Clark TD, 1999, CHEM-EUR J, V5, P782, DOI 10.1002/(SICI)1521-3765(19990201)5:2<782::AID-CHEM782>3.0.CO

[5]

2-A

[6]

DAVIDSON T, 1999, MAT SCI TECHNOLOGY S, pCH4

[7] Optical spectroscopy of isolated and aggregate hexabenzocoronene derivatives:: A study of self-assembling molecular nanowires [J].

Fleming, AJ ;

Coleman, JN ;

Dalton, AB ;

Fechtenkötter, A ;

Watson, MD ;

Müllen, K ;

Byrne, HJ ;

Blau, WJ .

JOURNAL OF PHYSICAL CHEMISTRY B, 2003, 107 (01) :37-43

[8] Polymerized lyotropic liquid crystal assemblies for materials applications [J].

Gin, DL ;

Gu, WQ ;

Pindzola, BA ;

Zhou, WJ .

ACCOUNTS OF CHEMICAL RESEARCH, 2001, 34 (12) :973-980

[9] Self-assembly and mineralization of peptide-amphiphile nanofibers [J].

Hartgerink, JD ;

Beniash, E ;

Stupp, SI .

SCIENCE, 2001, 294 (5547) :1684-1688

[10] Intramolecular cross-linking of helical folds: An approach to organic nanotubes [J].

Hecht, S ;

Khan, A .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2003, 42 (48) :6021-6024

← 1 2 3 →