Determination of fluid density confined in nanopore by means of NMR spectroscopy

被引:8
作者
Hiejima, Y [1 ]
Kanakubo, M [1 ]
Aizawa, T [1 ]
Kurata, Y [1 ]
Ikushima, Y [1 ]
机构
[1] AIST, Supercrit Fluid Res Ctr, Miyagino Ku, Sendai, Miyagi 9838551, Japan
关键词
D O I
10.1016/j.cplett.2005.04.059
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
We propose a new method, which determines the mean density of fluid confined in nanopore from the ratio of the NMR signals due to bulk and confined fluids. The present method is successfully applied to SF6 confined in porous Vycor glass in a wide range of the fluid phase. The mean density in nanopore accounts for the behavior of the chemical shift. (c) 2005 Elsevier B.V. All rights reserved.
引用
收藏
页码:344 / 347
页数:4
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