Unprecedented reduction of the uranyl ion [UO2]2+ into a polyoxo uranium(IV) cluster:: Synthesis and crystal structure of the first f-element oxide with a M6(μ3-O)8 core

被引：64

作者：

Berthet, JC ^{[1
]}

Thuéry, P ^{[1
]}

Ephritikhine, M ^{[1
]}

机构：

[1] CEA Saclay, DRECAM, Serv Chim Mol, DSM,CNRS,URA 331, F-91191 Gif Sur Yvette, France

来源：

CHEMICAL COMMUNICATIONS | 2005年 / 27期

关键词：

D O I：

10.1039/b503830h

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The smooth comproportionation reaction of the U( VI) and U( III) complexes UO2(OTf)(2) and U(OTf)(3), afforded the hexanuclear U( IV) oxide cluster [U-6(mu(3)-O)8(mu(2)-OTf)(8)( py) 8], a rare example of a metal oxide with a M-6(mu(3)-O)(8) core.

引用

页码：3415 / 3417

页数：3

共 49 条

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