Catalytic cycle for the asymmetric hydrogenation of prochiral ketones to chiral alcohols:: Direct hydride and proton transfer from chiral catalysts trans-Ru(H)2(diphosphine)(diamine) to ketones and direct addition of dihydrogen to the resulting hydridoamido complexes

被引:271
作者
Abdur-Rashid, K [1 ]
Faatz, M [1 ]
Lough, AJ [1 ]
Morris, RH [1 ]
机构
[1] Univ Toronto, Dept Chem, Toronto, ON M5S 3H6, Canada
关键词
D O I
10.1021/ja015902u
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
27
引用
收藏
页码:7473 / 7474
页数:2
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