Nucleobase-containing gelators

被引:123
作者
Araki, K [1 ]
Yoshikawa, I [1 ]
机构
[1] Univ Tokyo, Inst Ind Sci, Meguro Ku, Tokyo 1538505, Japan
来源
LOW MOLECULAR MASS GELATORS: DESIGN, SELF-ASSEMBLY, FUNCTION | 2005年 / 256卷
关键词
nucleobase; hydrogen bond; stacking interaction; hydrogel; organogel;
D O I
10.1007/b107173
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Nucleobases are nitrogenous heterocyclic compounds and have high ability to form directionally controlled multiple intermolecular interaction, i.e., in-plane multiple hydrogen-bonding interactions and stacking interactions perpendicular to the plane. Here the recent development of nucleobase-containing low molecular mass gelators in aqueous and organic systems is reviewed, and the self-assemblies of nucleobasecontaining small molecules and their arrangement within the gel are discussed from the molecular, and mesoscopic to the macroscopic level in regard to becoming a macroscale three-dimensional network. Brief overview of the nucleoside-containing supramolecular materials are also presented.
引用
收藏
页码:133 / 165
页数:33
相关论文
共 82 条