Post-synthetic modification of the metal-organic framework compound UiO-66

被引：351

作者：

Kandiah, Mathivathani

Usseglio, Sandro ^{[2
]}

Svelle, Stian ^{[2
]}

Olsbye, Unni ^{[2
]}

Lillerud, Karl Petter ^{[2
]}

Tilset, Mats ^{[1
]}

机构：

[1] Univ Oslo, Dept Chem, CTCC, N-0315 Oslo, Norway

[2] Univ Oslo, Dept Chem, InGAP, N-0315 Oslo, Norway

来源：

JOURNAL OF MATERIALS CHEMISTRY | 2010年 / 20卷 / 44期

关键词：

CATALYSIS; SORPTION;

D O I：

10.1039/c0jm02416c

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Post-synthetic modification is a viable route for the introduction of surface sites with new chemical properties in metal-organic framework compounds. Herein we demonstrate that it is possible to perform covalent post-synthetic modifications of the UiO-66-NH(2) MOF with four different acid anhydrides. FT-IR is employed to monitor the reactions and the extent of reaction depends on the bulkiness of the anhydrides. For the smallest one, acetic anhydride, 100% conversion to UiO-66-NHCOCH(3) was observed.

引用

收藏

页码：9848 / 9851

页数：4

相关论文

共 18 条

[1] THE CARBONYL INTENSITIES OF SOME SIMPLE AMIDES [J].

BROWN, TL ;

REGAN, JF ;

SCHUETZ, RD ;

STERNBERG, JC .

JOURNAL OF PHYSICAL CHEMISTRY, 1959, 63 (08) :1324-1325

[2] A new zirconium inorganic building brick forming metal organic frameworks with exceptional stability [J].

Cavka, Jasmina Hafizovic ;

Jakobsen, Soren ;

Olsbye, Unni ;

Guillou, Nathalie ;

Lamberti, Carlo ;

Bordiga, Silvia ;

Lillerud, Karl Petter .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2008, 130 (42) :13850-13851

[3] Chemical modification of a bridging ligand inside a metal-organic framework while maintaining the 3D structure [J].

Costa, Jose Sanchez ;

Gamez, Patrick ;

Black, Cory A. ;

Roubeau, Olivier ;

Teat, Simon J. ;

Reedijk, Jan .

EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2008, (10) :1551-1554

[4] ACETYLDIARYLAMINES BY ARYLATION OF ACETANILIDES - SOME APPLICATIONS AND LIMITATIONS [J].

FREEMAN, HS ;

BUTLER, JR ;

FREEDMAN, LD .

JOURNAL OF ORGANIC CHEMISTRY, 1978, 43 (26) :4975-4978

[5] Porous Chromium Terephthalate MIL-101 with Coordinatively Unsaturated Sites: Surface Functionalization, Encapsulation, Sorption and Catalysis [J].

Hong, Do-Young ;

Hwang, Young Kyu ;

Serre, Christian ;

Ferey, Gerard ;

Chang, Jong-San .

ADVANCED FUNCTIONAL MATERIALS, 2009, 19 (10) :1537-1552

[6] INFINITE POLYMERIC FRAMEWORKS CONSISTING OF 3 DIMENSIONALLY LINKED ROD-LIKE SEGMENTS [J].

HOSKINS, BF ;

ROBSON, R .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1989, 111 (15) :5962-5964

[7]

KANDIAH M, 2010, UNPUB

[8]

LETAW H, 1953, PHYS REV, V91, P235

[9] A homochiral metal-organic porous material for enantioselective separation and catalysis [J].

Seo, JS ;

Whang, D ;

Lee, H ;

Jun, SI ;

Oh, J ;

Jeon, YJ ;

Kim, K .

NATURE, 2000, 404 (6781) :982-986

[10]

Socrates G., 2002, Journal of the American Chemical Society, V124, DOI [10.1021/ja0153520, DOI 10.1021/JA0153520]