Mechanism of alkene aziridination in the [(biaryldiimine)CuI] catalyst system;: precise substrate orientation via two-centre binding

被引:84
作者
Gillespie, KM [1 ]
Crust, EJ [1 ]
Deeth, RJ [1 ]
Scott, P [1 ]
机构
[1] Univ Warwick, Dept Chem, Coventry CV4 7AL, W Midlands, England
关键词
D O I
10.1039/b101415n
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The highly enantioselective (less than or equal to 98%) aziridination of cinnamate esters is achieved using the title catalyst system via a concerted non-polar mechanism involving ancillary binding of carbonyl group to copper.
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页码:785 / 786
页数:2
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