Mechanism of alkene aziridination in the [(biaryldiimine)CuI] catalyst system;: precise substrate orientation via two-centre binding

被引：84

作者：

Gillespie, KM ^{[1
]}

Crust, EJ ^{[1
]}

Deeth, RJ ^{[1
]}

Scott, P ^{[1
]}

机构：

[1] Univ Warwick, Dept Chem, Coventry CV4 7AL, W Midlands, England

来源：

CHEMICAL COMMUNICATIONS | 2001年 / 08期

关键词：

D O I：

10.1039/b101415n

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The highly enantioselective (less than or equal to 98%) aziridination of cinnamate esters is achieved using the title catalyst system via a concerted non-polar mechanism involving ancillary binding of carbonyl group to copper.

引用

页码：785 / 786

页数：2

共 20 条

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