Tris(trimethylsilyl)silane as mediator in the radical-based allylation reactions of allyl and 2-functionalized allyl phenyl sulfones

被引：23

作者：

Chatgilialoglu, C ^{[1
]}

Alberti, A ^{[1
]}

Ballestri, M ^{[1
]}

Macciantelli, D ^{[1
]}

Curran, DP ^{[1
]}

机构：

[1] UNIV PITTSBURGH,DEPT CHEM,PITTSBURGH,PA 15260

来源：

TETRAHEDRON LETTERS | 1996年 / 37卷 / 35期

基金：

美国国家科学基金会; 美国国家卫生研究院;

关键词：

D O I：

10.1016/0040-4039(96)01355-X

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Radical allylations with 2-functionalized allyl phenyl sulfones have been performed by using ais(trimethylsilyl)silane as radical mediator. Yields varied from moderate to good depending on the nature of the starting materials. EPR studies on the alkyl radical adducts of allyl sulfones have been performed and conformational information has been obtained for the tert-butyl and tetrahydrofuranyl adducts of 2-carboxy allyl tris(trimethylsilyl)silane. Copyright (C) 1996 Elsevier Science Ltd

引用

页码：6391 / 6394

页数：4

共 11 条

[1]

[Anonymous], 1994, ELECT PARAMAGNETIC R

[2] INVESTIGATIONS OF STRUCTURE AND CONFORMATION .12. STRUCTURE OF AROMATIC SULFONYL RADICALS - ESR AND INDO MOLECULAR-ORBITAL STUDY [J].