Reversible thickening/thinning phenomena observed for polymer blend films in water media

被引：13

作者：

He, Y ^{[1
]}

Li, JC ^{[1
]}

Shuai, XT ^{[1
]}

Inoue, Y ^{[1
]}

机构：

[1] Tokyo Inst Technol, Dept Biomol Engn, Midori Ku, Yokohama, Kanagawa 2268501, Japan

来源：

MACROMOLECULES | 2001年 / 34卷 / 23期

关键词：

D O I：

10.1021/ma010991g

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

interesting phenomenon, the thickening and thinning of polymer films in the water media, was investigated in this paper. The studied polymer films were cast from atactic poly(R,S-3-hydroxybutyrate)/poly(4-vinylphenol) (PVPh) and syndiotactic poly(R,S-3-hydroxybutyrate)/PVPh blends solution. The physical properties of the blend films were characterized by differential scanning calorimetry (DSC), and the hydrogen-bonding network in the blends was characterized with the employment of Fourier transform infrared spectroscopy (FT-IR). The thickening and thinning process of the polymer films in water media was monitored by the measurement of the thickness. The effects of temperature and surfactants on the process were evaluated, furthermore, and the essence of the thickening and thinning of the polymer films was discussed.

引用

页码：8166 / 8172

页数：7

共 32 条

[1] PHYSICAL-PROPERTIES AND ENZYMATIC DEGRADABILITY OF POLYMER BLENDS OF BACTERIAL POLY[(R)-3-HYDROXYBUTYRATE] AND POLY[(R,S)-3-HYDROXYBUTYRATE] STEREOISOMERS [J].

ABE, H ;

MATSUBARA, I ;

DOI, Y .

MACROMOLECULES, 1995, 28 (04) :844-853

[2]

Akiba I, 1997, POLYM NETWORK BLEND, V7, P147

[3] Phase structure and biodegradation of the bacterial poly(3-hydroxybutyric acid)/chemosynthetic poly(3-hydroxypropionic acid) blend [J].

Cao, A ;

Asakawa, N ;

Yoshie, N ;

Inoue, Y .

POLYMER JOURNAL, 1998, 30 (09) :743-752

[4] Solid structure and biodegradation of the compositionally fractionated poly(3-hydroxybutyric acid-co-3-hydroxypropionic acid)s [J].

Cao, A ;

Arai, Y ;

Yoshie, N ;

Kasuya, KI ;

Doi, Y ;

Inoue, Y .

POLYMER, 1999, 40 (24) :6821-6830

[5]

Coleman M. M., 1991, SPECIFIC INTERACTION

[6]

Coleman MM, 1998, J POLYM SCI POL PHYS, V36, P1579, DOI 10.1002/(SICI)1099-0488(19980715)36:9<1579::AID-POLB15>3.0.CO

[7]

2-2

[8] HYDROGEN-BONDED POLYMER BLENDS [J].

COLEMAN, MM ;

PAINTER, PC .

PROGRESS IN POLYMER SCIENCE, 1995, 20 (01) :1-59

[9]

He Y, 2000, J POLYM SCI POL PHYS, V38, P1848, DOI 10.1002/1099-0488(20000715)38:14<1848::AID-POLB30>3.0.CO

[10]

2-F

← 1 2 3 4 →