A molecular dynamics investigation of the structural characteristics of amorphous and annealed poly(vinylidene fluoride) and vinylidene fluoride-trifluoroethylene copolymers

被引：20

作者：

Holman, RW ^{[1
]}

Kavarnos, GJ ^{[1
]}

机构：

[1] USN,UNDERSEA WARFARE CTR,NEW LONDON DETACHMENT,SUBMARINE SONAR DEPT,NEW LONDON,CT 06320

来源：

POLYMER | 1996年 / 37卷 / 09期

关键词：

poly(vinylidene fluoride); conformational analysis; molecular dynamics;

D O I：

10.1016/0032-3861(96)83721-9

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Molecular dynamics (MD) computations predict that the extent of gauche-character for poly(vinylidene fluoride) (PVDF) is greater than that of its 50 mol% copolymer with trifluoroethylene, at both high temperatures and after annealing. PVDF is enriched in gauche-conformations upon cooling whereas the copolymer is enriched in trans-conformations. The MD results are consistent with the experimental trends observed for these polymers. Published by Elsevier Science Ltd.

引用

页码：1697 / 1701

页数：5

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