Pauson-Khand cycloaddition reactions of chiral ynamides.: Observation of an unusual endo-addition with norbornadiene

被引：43

作者：

Shen, LC ^{[1
]}

Hsung, RP ^{[1
]}

机构：

[1] Univ Minnesota, Dept Chem, Minneapolis, MN 55455 USA

来源：

TETRAHEDRON LETTERS | 2003年 / 44卷 / 52期

基金：

美国国家科学基金会;

关键词：

D O I：

10.1016/j.tetlet.2003.10.064

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Pauson-K hand cycloadditions using chiral ynamides are achieved in modest to good yields with excellent regioselectivity and modest stereoselectivity. An unusual endo addition is found when using norbornadiene and substituted ynamides, leading to cycloadducts that were not observed in previous studies using ynamides or ynamines. (C) 2003 Elsevier Ltd. All rights reserved.

引用

页码：9353 / 9358

页数：6

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